High Temperature Oxidation Behaviors of CNTs/MoSi2 Composites

Article Preview

Abstract:

Molybdenum disilicide (MoSi2) matrix composites with various contents of carbon nanotubes (CNTs) were fabricated by sintering in vacuum at 1550°C for 1 h. The oxidation behaviors of CNTs/MoSi2 composites at 1300°C for 200 h in air were studied. Results showed that MoSi2 matrix composites with no more than 8 % CNTs in volume had good oxidation resistance at 1300 °C, although addition of CNTs reduced the high temperature oxidation resistance of MoSi2. An approximate linear relationship was found between the weight gain of CNTs/MoSi2 composites and the content of CNTs. The oxidation resistance of CNTs/MoSi2 composites at high temperature decreased with the increasing of CNTs contents. Since the gaseous products were formed during the oxidation process and escaped from the oxide film, the protective film became loose which offered channels for the oxygen soaking into the composites. Thus the oxidation resistance of CNTs/MoSi2 composites was decreased.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

15-19

Citation:

Online since:

January 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A.K. Vasudevan, J.J. Petrovic, A comparative overview of molybdenum disilicide composites, Mater. Sci. Eng. 155 (1992) 1–17.

Google Scholar

[2] J.J. Petrovic, Key development in high temperature structural silicide, Mater. Sci. Eng. 261 (1999) 1–5.

Google Scholar

[3] J.H. Yan, H.M. Xu, H.A. Zhang, S.W. Tang, MoSi2 oxidation resistance coatings for Mo5Si3/MoSi2 composites, Rare Metals. 4 (2009) 418-422.

DOI: 10.1007/s12598-009-0081-8

Google Scholar

[4] D. Sciti, M. Brach, A. Bellosi, Long-term oxidation behavior and mechanical strength degradation of a pressurelessly sintered ZrB2–MoSi2 ceramic, Scripta Mater. 53 (2005) 1297–1302.

DOI: 10.1016/j.scriptamat.2005.07.026

Google Scholar

[5] D. Sciti, M. Brach, A. Bellosi, Oxidation behavior of a pressureless sintered ZrB2–MoSi2 ceramic composite, J. Mater. Res. 20 (2005) 922–930.

DOI: 10.1557/jmr.2005.0111

Google Scholar

[6] G. Magnani, A. Brentari, E. Burresi, A. Coglitore, Mechanical properties and oxidation behavior of silicon carbide–molybdenum silicides composites, Ceram. Int. 39 (2013) 3345–3351.

DOI: 10.1016/j.ceramint.2012.10.024

Google Scholar

[7] H.A. Zhang, H.J. Wu, S.Y. Gu, Preparation and properties of MoSi2 based composites reinforced by carbon nanotubes, Ceram. Int. 39 (2013) 7401–7405.

DOI: 10.1016/j.ceramint.2013.02.083

Google Scholar

[8] A.A. Sharif, High-temperature oxidation of MoSi2, J. Mater. Sci. 45 (2010) 865–870.

Google Scholar

[9] P.Z. Gao, S.T. Huang, W.X. Wang, H.N. Xiao, Oxidation Resistance and Mechanism of MoSi2-Recystallized SiC Composites at Elevated Temperature, J. Chin. Ceram. Soc. 40 (2012) 789–795.

Google Scholar

[10] H.A. Zhang, H.J. Wu, S.Y. Gu, Preparation and properties of MoSi2 based composites reinforced by carbon nanotubes, Ceram. Int. 39 (2013) 7401–7405.

DOI: 10.1016/j.ceramint.2013.02.083

Google Scholar

[11] J.J. Xi, A.B. Amina, L.Q. Wang, Research on Oxidation Behavior of SiC/MoSi2 Comp osites at 1300 °C, Mater. Rev. 24 (2010) 56–59.

Google Scholar