Fabrication of Three-Dimensional Porous Sn Films as Anode for Li-Ion Batteries

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A polystyrene spheres (PS) coated copper foil was adopted as a template to prepare three-dimensional (3D) porous Sn film electrode. The PS colloidal spheres were synthesized through emulsion polymerization and spin-coated on copper foil. Then Tin was electrodeposited on the template foil, following by etching in tetrahydrofuran to remove PS template. The obtained Sn film has a honeycomb-like porous structure and showed improved electrochemical performance.

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567-571

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February 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. Cabana, L. Monconduit, D. Larcher et al. Adv. Mater. 22 (2010) E170–E192.

Google Scholar

[2] L. Qie, W. Chen, Z. Wang et al. Adv. Mater. 24 (2012) 2047–(2050).

Google Scholar

[3] S. Zhang, Y. Xing, T. Jiang, et al. J. Power Sources 196 (2011) 6915–6919.

Google Scholar

[4] S. C. Nam, Y. S. Yoon, W. I. Cho, et al. J. Electrochem. Soc. 148 (2001) A220-A223.

Google Scholar

[5] N. Tamura, R. Ohshita, M. Fujimoto, et al. J. Electrochem. Soc. 150 (2003) A679-A683.

Google Scholar

[6] L. Wang, S. Kitamura, T. Sonoda, et al. J. Electrochem. Soc. 150 (2003) A1346-A1350.

Google Scholar

[7] Weihua Pu, Xiangming He, Jianguo Ren, et al. Electrochim. Acta 50 (2005) 4140-4145.

Google Scholar

[8] Weixiang Chen, Jimyang Lee, Zhaolin Liu. Carbon 41 (2003) 959-966.

Google Scholar

[9] B. T. Holland, C. F. Blanford, A. Stein. Science 281 (1998) 538-540.

Google Scholar

[10] L. Mercier, T. Pinnavaia. Adv. Mater. 9 (1997) 500-503.

Google Scholar

[11] X. Feng, G. Fryxell, L. Q. Wang, et al. Science 276 (1997) 923-926.

Google Scholar

[12] L. J. Fu, T. Zhang, Q. Cao, et al. Electrochem. Commun. 9 (2007) 2140–2144.

Google Scholar

[13] X. H. Xia, J. P. Tu, J. Y. Xiang, et al. J. Power Sources 195 (2010) 2014-(2022).

Google Scholar

[14] Yanan Fu, Zhengguo Jin, Zhifeng Liu et al. J. Eur. Ceram. Soc. 27 (2007) 2223-2228.

Google Scholar

[15] I. A. Courtney, J. R. Dahn. J. Electrochem. Soc. 144 (1999) 2045-(2052).

Google Scholar

[16] L. Y. Beaulieu, S. D. Beattie, T. D. Hatchard. J. Electrochem. Soc. 150 (2003) A419-A424.

Google Scholar

[17] J. O. Besenhard, J. Yang, M. Winter. J. Power Sources, 68 (1997) 87-90.

Google Scholar

[18] M. Winter, J. Besenhard. Electrochimica Acta 45 (1999) 31-50.

Google Scholar

[19] Haipeng Zhao, Changyin Jiang, Xiangming He. J. Membrane Sci. 3 (2008) 1-6.

Google Scholar

[20] C. Kwon, S. Cheon, J. M. Song, et al. J. Power Sources 93 (2001) 145-150.

Google Scholar

[21] C. D. Gu, Y. J. Mai, J. P. Zhou, et al. J. Power Sources 214 (2012) 200-207.

Google Scholar

[22] Leigang Xue, Zhenghao Fu, Yu Yao, et al. Electrochim. Acta 55 (2010) 7310-7314.

Google Scholar