NIR and Upconversion Luminescence Properties of Nd3+ Doped in Gd2O3-CaO-SiO2-B2O3 Glass System

S. Insiripong; S. Kaewjeang; U. Maghanemi; H.J. Kim; N. Chanthima; J. Kaewkhao

doi:10.4028/www.scientific.net/AMM.548-549.124

Paper Titles

Performance Evaluation of Agarwood Distillation Waste as Retarder for High Strength Oilwell Cement
p.101

Filled-NR Conductive Thin Film: A Simple Route of Graphene Dispersion in Natural Rubber Latex
p.106

A Study on Effect of PFA on Stabilized Material Using Direct Shear Test
p.111

Enhanced Thermal Conductivity of Nanofluid by Synergistic Effect of Multi-Walled Carbon Nanotubes and Fe₂O₃ Nanoparticles
p.118

NIR and Upconversion Luminescence Properties of Nd³⁺ Doped in Gd₂O₃-CaO-SiO₂-B₂O₃ Glass System
p.124

To Produce Electromagnetic Shielding Material from Lignin of Black Liquor
p.129

Investigation into the Differences Chemical Properties of Laser Sintering Polymer Powders Using Fourier Transform Infrared Spectroscopy
p.133

Chiral Structure in a Hard/Soft/Hard Layered Magnet
p.137

Effect of Aging Treatment on Structural and Mechanical Properties of CuCrZr/AlN Nanocomposites
p.141

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 548-549NIR and Upconversion Luminescence Properties of...

NIR and Upconversion Luminescence Properties of Nd³⁺ Doped in Gd₂O₃-CaO-SiO₂-B₂O₃ Glass System

Abstract:

In this work, properties of Nd³⁺in Gd₂O₃-CaO-SiO₂-B₂O₃glass systems with composition 25Gd₂O₃-10CaO-10SiO₂-(55-x)B₂O₃-xNd₂O₃ where x = 0.0, 0.5, 1.0, 1.5, 2.0 and 2.5 mol% were investigated. The optical absorption spectra show peaks at ⁴F_3/2(877 nm) , ⁴F_5/2+²H_9/2(802 nm), ⁴F_7/2+⁴S_3/2(743 nm), ⁴F_9/2(682 nm), ²H_11/2(627 nm), ²G_7/2+⁴G_5/2(582 nm), ⁴G_7/2+²K_13/2(527 nm), ⁴G_11/2(481 nm), ²P_1/2(427 nm) and ²L_15/2+ ⁴D_1/2+ ¹I_11/2+ ⁴D_5/2+ ⁴D_3/2(355 nm) reflecting the Nd³⁺ ions in glass matrices. The densities were increased with increasing of Nd₂O₃ concentration. This indicates the increase of the molecular weight by the replacement of B₂O₃ with a heavier Nd₂O₃oxide in the glass. The upconversion luminescence spectra show bands at 393 nm for all Nd₂O₃ concentration and the strongest intensity from 2.5 % mol of Nd₂O₃was obtained. For NIR luminescence, the intensity of Nd³⁺ emission spectra increases with increasing concentrations of Nd³⁺ up to 1.5 mol% and beyond 1.5 mol% the concentration quenching is observed.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volumes 548-549)

Pages:

124-128

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.548-549.124

Citation:

Cite this paper

Online since:

April 2014

Authors:

S. Insiripong*, S. Kaewjeang, U. Maghanemi, H.J. Kim, N. Chanthima, J. Kaewkhao

Keywords:

Glass, Luminescence, Nd³⁺, Optical, Physical

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] P. Dorenbos The 4fn«4fn-15d transitions of the trivalent lanthanides in halogenides and chalcogenides, J. Luminescence, 91 (2000) 91-106.

DOI: 10.1016/s0022-2313(00)00197-6

Google Scholar

[2] J. M. Park, H. J. Kim, S. Kim, P. Limsuwan, J. Kaewkhao, Luminescence Property of Rare-Earth Doped Bismuth-Borate Glasses, Procedia Engineering, 32 (2012) 855-861.

DOI: 10.1016/j.proeng.2012.02.023

Google Scholar

[3] C. W. Thiel, Y. Sun, R. L. Cone, Photonic materials and devices progress in relating rare-earth ion 4f and 5d energy levels to host bands in optical materials for hole burning, quantum information and phosphors, J. Modern Optics, 49 (2002).

DOI: 10.1080/0950034021000011491

Google Scholar

[4] J.M. Park, H. J. Kim, S. Kim, J. Cheon, J. Kaewkhao, P. Limsuwan, S. Iniripong, X-Ray and Proton luminescenceof bismuth-borate glasses, J. Korean Phys. Soc, 59 (2011) 657-660.

DOI: 10.3938/jkps.59.657

Google Scholar

[5] P. Chimalawong, J. Kaewkhao, C. Kedkaew, P. Limsuwan, Optical and electronic polarizability investigation of Nd3+- doped soda-lime silicate glasses, J. Physics and Chemistry of Solids, 71 (2010) 965–970.

DOI: 10.1016/j.jpcs.2010.03.044

Google Scholar

[6] J. Wan, L. Cheng, J. Sun,H. Zhong,X. Li,W. Lu,Y. Tian, B. Wang,B. Chen, Composition-dependentspectroscopicpropertiesofNd3+-doped tellurite–germanateglasses, Physica B, 405 (2010) 1958–(1963).

DOI: 10.1016/j.physb.2010.01.051

Google Scholar

[7] K. Annapurna, R.N. Dwivedi, P. Kundu, S. Buddhudu, NIR emission and upconversion luminescence spectra of Nd3+: ZnO–SiO2–B2O3 glass, J. Materials Letters, 57 (2003) 2095– (2098).

DOI: 10.1016/s0167-577x(02)01144-8

Google Scholar

[8] J. Kaewkhao, H.J. Kim,S. Insiripong,N. Chanthima, S. Kaewjaeng, U. Maghanemi, Upconversion Luminescence Study of Er3+ in Gadolinium-Calcium-Silicoborate Glasses, Advanced Materials Research, 770 (2011) 249-253.

DOI: 10.4028/www.scientific.net/amr.770.249

Google Scholar

[9] G. H. Dieke, H. Crosswhite, Spectra and Energy Levels of Rare Earth Ions in Crystals, Interscience, New York (1968).

Google Scholar

[10] S. Mohan, K. S. Thind, G. Sharma, Effect of Nd3+ Concentration on the Physical and Absorption Properties of Sodium-Lead-Borate Glasses, Brazilian Journal of Physics, 37 (2007) 1306-1313.

DOI: 10.1590/s0103-97332007000800019

Google Scholar

[11] B. S. Reddy, S. Buddhudu, S. R. K. Rao, P. N. Babu, Spectral analysis of Nd3+ & Er3+: B2O3-(TeO2/CdO/ZnO)-Li2O-AlF3 glasses, J. optoelectronics and advanced materials, 10 (2008) 2777 – 2781.

Google Scholar

[12] Sk. Mahamuda, K. Swapna, A. Srinivasa Rao, M. Jayasimhadri, T. Sasikala, K. Pavani, L. Rama Moorthy, Spectroscopic properties and luminescence behavior of Nd3+ doped zinc alumino bismuth borate glasses, J. Physics and Chemistry of Solids, 74 (2013).

DOI: 10.1016/j.jpcs.2013.04.009

Google Scholar