Study of Corrosion-Resistance on Biomedical Coating by Different Surface Treatments

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Abstract:

The porous titanium alloy prepared by gel-casting methods was used as precursor and the composite coatings with hydroxyapatite HA/TiO2 were prepared on the precursor which was treated by NaOH solution, H2O2 + NH3 solution, HF+HNO3, PdCl2 solution to improve the capability of coatings. The microstructure was examined by SEM and the corrosion behavior of the coating layers in the simulated body fluids (SBF) was evaluated by potentiodynamic polarization test and impedance plots. The results show that the corrosion resistance of samples using PdCl2 treatment is superior to else others. The PdCl2 processing provides the substrate surface an excellent oxide film, which plays a key role in the corrosion resistance of coating. The thickness of the coatings is about 60μm and the surface morphologies are more uniform than the others and have no crack.

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391-395

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May 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Yildirim O S, Aksakal B, Celika H, et al. An investigation of the effects of hydroxyapatite coating on the fixation strength of cortical screws [J]. Medical Engineering & Physics, 27(2005): 221.

DOI: 10.1016/j.medengphy.2004.10.006

Google Scholar

[2] Uchida M, Oyane A, Kim H M, et al. Biomimetic Coating of Laminin-Apatite Composite on Titanium Metal and Its Excellent Cell-Adhesive Properties[J]. Adv Mater, 16(13) (2004): 1071.

DOI: 10.1002/adma.200400152

Google Scholar

[3] Boon Sing Ng, Ingegerd Annergren, Andrew M Soutar, et al. Characterisation of a duplex TiO2/CaP coating on Ti6Al4V for hard tissue replacement[J]. Biomaterials, 26(2005): 1087.

DOI: 10.1016/j.biomaterials.2004.04.022

Google Scholar

[4] Zheng C Y, Li S J, Tao X J, et al. Calcium phosphate coating of Ti-Nb-Zr-Sn titanium alloy [J]. Mater Sci Eng C, 27(2007): 824.

DOI: 10.1016/j.msec.2006.09.021

Google Scholar

[5] Spriano S. Surface properties and cell response of low metal ionreleaseTi-6Al-7Nb alloy after multi-step chemical and thermal treatments[J]. Biomaterials, 26(2005): 1219.

DOI: 10.1016/j.biomaterials.2004.04.026

Google Scholar

[6] WEI M, Kim H M, Kokubo T, Evans J H, et al. Optimising the bioactivity of alkaline treated titanium alloy[J]. Mater Sci Eng C, 20(2002): 125.

DOI: 10.1016/s0928-4931(02)00022-x

Google Scholar

[7] Li Y, Guo Z, Hao J, et al. Porosity and mechanical properties of porous titanium fabricated by gel-casting[J]. Rare Metals. 27(3) (2008): 282.

DOI: 10.1016/s1001-0521(08)60130-8

Google Scholar

[8] WEI M, RUYS A J, SWAIN M V, et al. Interfacial bond strength of electrophoretically deposited hydroxyapatite coating on metals[J]. J Mater Sci: Mater in Med, 10(1999): 401.

Google Scholar

[9] Cao C N, Zang J Q. An introduction to electrochemical impedance spectroscopy [M]. Beijing:Science Press, (2002).

Google Scholar

[10] Yang H G, Zhu X M, Lei M K. Evaluation of porosity of hard coatings by corrosion electrochemistry [J].CORROSION SCIENCE AND PROTECTION TECHNOLOGY. 17(6) (2005): 413.

Google Scholar