The Preparation and Characterization of ZnO/Graphene Nanocomposites

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Graphene-based composites now has been payed more and more attention to because it can make up many shortcomings of the pure single-layer graphene.In many papers ,there are one same phenomenon said that graphene can not be well dispersed in matrix since it’s high specific surface area and high surface energy.In this work,we reported the preparation of ZnO/graphene nanocomposites through the way of situ-reaction in the surface of graphite oxide.Then,the nanocomposites were characterized by X-ray diffraction (XRD), Fourier Transform-Infared spectroscopy (FTIR),transmission electron microscopy (TEM), and thermogravimetry (TG). The results indicated that the graphene oxide had been reduced by hydrazine hydrate and the ZnO crystal attached to the surface of graphene well.The ZnO/graphene nanocomposites can be expected to be dispersed in some kinds of rubber to improve their electric and thermal conductivities in the following experiments.

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21-27

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July 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Ji Won Suk, Alexander Kitt, et al, Transfer of CVD-Grown monolayer graphene onto arbitrary substrates, ACSnano. 56(2011)916-6924.

DOI: 10.1021/nn201207c

Google Scholar

[2] Jing-xiang Zhao, Hong-xia wang, Bo Gao, et al, Chemical functionalization of graphene via aryne cycloaddition: a theoretical study, Springer-Verlag. 2011, 10. 1007/s00894-011-1309-8.

Google Scholar

[3] Zhou Wang, Xiu-zhi Tang, Zhong-Zhen Yu, et al. Dispersion of graphene oxide and its flame retardancy effect on epoxy nanocomposites, Chinese Journal of Polymer Science. 2 (2011) 368-376.

DOI: 10.1007/s10118-011-1037-7

Google Scholar

[4] Haiqing Hu, Yin Liu, Qingnian Wang, et al, A study on the preparation of highly conductive grapheme, Materials Letters. 65(2011) 2582-2584.

Google Scholar

[5] K.S. Novoselov, A.K. Geim, S.V., et al, Science. 306(2004)666–73.

Google Scholar

[6] D. L. Nika E.P. Pokatilov A.S. Askerov, et a1, Phonon thermal conduction in grapheme: Role of Umklapp and edge roughness scattering, Phys. Rev.B. 79(2009)155413.

DOI: 10.1103/physrevb.79.155413

Google Scholar

[7] Alexander A, Balandin, Suchismita Ghosh, et a1. Superior thermal conductivity of single-layer grapheme, Nano Lett. 8(2008): 902-907.

Google Scholar

[8] Sheng Kai-Xuan, Xu Yu-Xi, Li Chun, et al. High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide, New Carbon Materials. 26(2011)102-106.

DOI: 10.1016/s1872-5805(11)60062-0

Google Scholar

[9] Yu Li, Qihua Wang, Tingmei Wang, et al, Preparation and tribological properties of graphene oxide/nitrile rubber nanocomposites, J Mater Sci . 47 (2012)730–738.

DOI: 10.1007/s10853-011-5846-4

Google Scholar

[10] R. Kaur, A .V. Singh, et al, Physical properties of natively textured yttrium doped zinc oxide films by sol-gel, Journal of Materials Science: Materials In Electronics. 16 (2005) 649– 655.

DOI: 10.1007/s10854-005-3740-z

Google Scholar

[11] Zhengyuan Ji, Jili Wu, Xiaoping Shen, et al, Preparation and characterization of graphene/NiO nanocomposites, J Mater Sci . (2011) 46: 1190–1195.

DOI: 10.1007/s10853-010-4892-7

Google Scholar

[12] Zumdahl, S. Steven, Chemical Principles, 6th Ed., Houghton Mifflin Company, Boston, (2009).

Google Scholar

[13] Ma Ru yan, Gao yuan-feng, Pang Xian-yong, The preparation of nanometer zinc hydroxide and the phase transition research, J Shanxi Agric Univ (Natural Science Edition). 31 (2011) : 105~108.

Google Scholar

[14] Dapeng Wu, Yi Jiang, Junli Liu, et al, Template route to chemically engineering cavities at nanoscale: a case study of Zn(OH)2 template, Nanoscale Res Lett . 5 (2010)1779–1787.

DOI: 10.1007/s11671-010-9711-1

Google Scholar

[15] Wang Lina, Chen Chengmeng, Yang Yonggang, et al, The preparation and properties of graphene oxide sheets/phenolic resin composites, Materials Review. 24(2010) : 85-59.

Google Scholar

[16] Guo Peng, Preparation,assembly and application of graphene, Beijing University of Chemical Technology. (2010).

Google Scholar

[17] Olga Khvostikova, Helmut Hermann, Horst Wendrock, et al, Effect of the microstructure on the intercalation and exfoliation behaviour of graphite, J Mater Sci. 46 (2011): 2422–2430.

DOI: 10.1007/s10853-010-5088-x

Google Scholar

[18] Han Dong, Ren Xiang-ling, Chen Dong, et al, Preparation and photocatalytic property of ZnO nanoparticles, Photographic Science and Photochemistry. 23(2005): 52-55.

Google Scholar

[19] S.C. Singh, Effect of oxygen injection on the size and compositional evolution of ZnO/Zn(OH)2 nanocomposite synthesized by pulsed laser ablation in distilled water, Springer, J Nanopart Res. 13 (2011)4143–4152.

DOI: 10.1007/s11051-011-0359-2

Google Scholar