Mechanical Properties of DGEBA/Amidoamine Blend at Non-Stoichiometric Ratios

Article Preview

Abstract:

In this paper, the effect of varying mixing ratio of Diglycidyl ether of bisphenol A (DGEBA)/aliphatic amidoamine hardener on the behavior of dynamic cure profile and mechanical properties of the resulting thermoset was investigated. Epoxy/hardener sample with a stoichiometric mixing ratio of 2:1 are tested against non-stoichiometric ratios of 3:1 and 4:1. The tensile, flexural, and hardness properties of the specimens were measured while SEM is employed to investigate the fracture surface and analyze the failure. Results showed that epoxy enriched samples (non-stoichiometric) has a much brittle behavior and the DGEBA/hardener samples tend to fail under relatively small strain.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

63-71

Citation:

Online since:

July 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] D'Almeida. M. R. J., De Menezes. W. G., and Monteiro. N. S., Ageing of the DGEBA/TETA Epoxy System with Off-Stoichiometric Compositions, Materials Research, Vol. 6 (3), pp.415-420 (2003).

DOI: 10.1590/s1516-14392003000300017

Google Scholar

[2] Tanaka, Y. and Bauer, R. S., Curing Reactions. in Epoxy Resins Chemistry and Technology, May, C. A., 2nd Ed., Marcel Dekker, Inc., New York, 285 (1988).

Google Scholar

[3] Norman E. Dowling, Mechanical behaviour of materials, Engineering Methods for Deformation, Fracture, and Fatigue. , Ed. 4th, pp.100-234.

Google Scholar

[4] Mariam, E.A. (2010), A Study on the Effect of Hardener on the Mechanical Properties of Epoxy Resin, MSc Thesis., University of Technology: Republic of Iraq.

Google Scholar

[5] Odegard, G.M. and Bandyopadhyay. A., Physical Aging of Epoxy Polymers and Their Composites, Journal of Polymer Science Part B: Polymer Physics, Vol. 49 (24, pp.1695-1716 (2011).

DOI: 10.1002/polb.22384

Google Scholar

[6] Shaorong. L., Ban. J., Yu. C., and Deng.W., Properties of Epoxy Resins Modified with Liquid Crystalline Polyurethane, Irnanian Polymer Journal, Vol. 19(9), pp.669-678 (2010).

Google Scholar

[7] Ferreira J.A.M., Costa J.D.M., Reis. P.N.B., and Capela.C., A Study on the Stiffness and Toughness of Enhanced Nanofilled Epoxy composites, Anales de Mecanica de la Fractura, Vol. 1(28), pp.291-296 (2011).

Google Scholar

[8] Jean-Marie. B, Composite Materials. Mechanical Behavior and Structural Analysis., pp.15-23.

Google Scholar

[9] S. Grishchuk1, Z. Mbhele2, S. Schmitt1, J. Karger-Kocsis, Structure, Thermal and Fracture Mechanical Properties of Benzoxazine-Modified Amine-cured DGEBA Epoxy Resins, Express Polymer Letters, Vol. 5 (3), pp.273-282(2011).

DOI: 10.3144/expresspolymlett.2011.27

Google Scholar

[10] Sherman, D. and Brandon, D., Mechanical Properties of Hard Materials and Their Relation to Microstructure, Advance Engineering of Material, Vol. 1, no. 3-4, pp.161-181 (1999).

Google Scholar

[11] Cuddihy, E., Moacanin, Superposition of Dynamic Mechanical Properties in the Glassy State, Journal of Polymer Science Part A-2(Polymer Physics), Vol. (9), pp.1627-1634(1970).

DOI: 10.1002/pol.1970.160080915

Google Scholar