Analysis on the Anodizing Process of AZ31 Magnesium Alloy in an Environmental Friendly Alkaline Electrolyte

Article Preview

Abstract:

AZ31 magnesium alloy was anodized in an environmental friendly electrolyte containing 50 g/l NaOH + 40 g/l Na2B4O7·10H2O + 60 g/l Na2SiO3·9H2O. The voltage transient was recorded in anodizing process. The surface morphology of anodizing film was examined by SEM. The corrosion resistance of the anodizing film was characterized by electrochemical impedance spectroscopy and potentiodynamic polarization techniques. The results show that the anodizing process can be divided to four stages according to the voltage transient. The anodizing film obtained at a current density of 20 mA·cm-2 for 15 minutes has the optimum corrosion resistance.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

128-131

Citation:

Online since:

October 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] H.K. Lim, D.H. Kim, J.Y. Lee, et al, Effects of alloying elements on microstructures and mechanical properties of wrought Mg-MM-Sn alloy, J. Alloy. Compd. 468(2009)308-314.

DOI: 10.1016/j.jallcom.2007.12.098

Google Scholar

[2] L. Wang, T. Shinohara, B.P. Zhang, Influence of chloride, sulfate and bicarbonate anions on the corrosion behavior of AZ31 magnesium alloy, J. Alloy. Compd. 496(2010) 500-507.

DOI: 10.1016/j.jallcom.2010.02.088

Google Scholar

[3] G.L. Song, Recent progress in corrosion and protection of magnesium alloys-An over of cast's research work, Adv. Eng. Mater. 7 (2005) 563-586.

DOI: 10.1002/adem.200500013

Google Scholar

[4] D. Nam, W.C. Kim, J.G. Kima, et al, Corrosion resistance of Mg-5Al-xSr alloys, J. Alloy. Compd. 509(2011) 4839-4847.

DOI: 10.1016/j.jallcom.2011.01.187

Google Scholar

[5] Y. Choia, S. Salman, K. Kuroda, et al. Improvement in corrosion characteristics of AZ31 Mg alloy by square pulse anodizing between transpassive and active regions, Corros. Sci. 63(2012) 5-11.

DOI: 10.1016/j.corsci.2012.02.010

Google Scholar

[6] W. Li, W. Li, L. Zhu, et al. Non-sparking anodization process of AZ91D magnesium alloy under low AC voltage, Mater. Sci. Eng. B. 178(2013) 417-424.

DOI: 10.1016/j.mseb.2013.01.008

Google Scholar

[7] H.Y. Hsiao, H.C. Tsung, W.T. Tsai, Anodization of AZ91D magnesium alloy in silicate-containing electrolytes, Surf. Coat. Tech. 199(2005) 127-134.

DOI: 10.1016/j.surfcoat.2004.12.010

Google Scholar

[8] L.J. Zhang, J.J. Fan, Z. Zhang, et al, Study on the anodic film formation process of AZ91D magnesium alloy, Electrochim. Acta 52(2007) 5325-5333.

DOI: 10.1016/j.electacta.2006.12.083

Google Scholar

[9] H.A. Evangelides, Method of electrolytically coating magnesium and electrolyte therefore, U.S. Pat. 2723952, 1955. 11. 15.

Google Scholar

[10] C.C. Dow, Bath for and method of producing a corrosion resistant coating upon light metals, G.B. Pat. 762195, 1956. 11. 28.

Google Scholar

[11] Y. Liu, Z. Wei, F. Yang, et al, Environmental friendly anodizing of AZ91D magnesium alloy in alkaline borate-benzoate electrolyte, J. Alloy. Compd. 509 (2011) 6440-6446.

DOI: 10.1016/j.jallcom.2011.03.083

Google Scholar

[12] L. Chai, X. Yu, Z. Yang, et al, Anodizing of magnesium alloy AZ31 in alkaline solutions with silicate under continuous sparking, Corros. Sci. 50 (2008) 3274-3279.

DOI: 10.1016/j.corsci.2008.08.038

Google Scholar