Chloroform Gas Sensor Based on Chitosan Biopolymer

Article Preview

Abstract:

Chloroform classified as one of the hazardous chemical to human. Therefore, monitoring the chloroform concentration in air is vital. In this study, chitosan powder was dissolved in 2% of acetic acid to form chitosan solution gel. It was subsequently deposited on printed circuit board (PCB) by using electrochemical deposition technique. The response of the chitosan sensor towards chloroform was tested via electrical testing by exposing different chloroform concentration ranging from 10 ppm, 20 ppm, 30 ppm, 40 ppm, and 50 ppm using air exposure technique. The response of the chitosan sensor towards chloroform was recorded as output voltage. Sensing properties of the chitosan sensor which include sensitivity, stability, recovery, and repeatability were studied. The electrical result showed that output voltage increases as the concentration of chloroform increases. All the sensing properties were achieved. The structure characterization of the chitosan was studied using Fourier Transform Infrared Spectroscopy (FTIR). The appearance of N-H and O-H groups in FTIR spectrum of chitosan film provides evidence that the domain functional group exist in chitosan after it was processed into film.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

45-49

Citation:

Online since:

October 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] P. M. Perillo and D. F. Rodríguez: A room temperature chloroform sensor using TiO2 nanotubes. Sensors and Actuators B Vol 193 (2014), p.263– 266.

DOI: 10.1016/j.snb.2013.11.075

Google Scholar

[2] P. Ncube, R. W. M. Krause, and B. B. Mamba: Detection of chloroform in water using an azo dye-modified b-cyclodextrin – Epichlorohydrin copolymer as a fluorescent probe. Physics and Chemistry of the Earth (2013), in press.

DOI: 10.1016/j.pce.2013.10.009

Google Scholar

[3] S. Sharma, C. Nirkhe, S. Pethkar, and A. A. Athawale: Chloroform vapour sensor based on copper/polyanniline nanocomposite. Sensor and Actuators B Vol 85 (2002), pp.131-136.

DOI: 10.1016/s0925-4005(02)00064-3

Google Scholar

[4] P. Kar and A. Choudhury: Carboxylic acid functionalized multi-walled carbon nanotube doped polyanniline for chloroform sensor, sensor and Actuators B, Vol 183 (2014), pp.25-33.

DOI: 10.1016/j.snb.2013.03.093

Google Scholar

[5] P. Dykstra, J. Hao, S. T. Koev, G. F. Payne, L. Yu, and R. Ghodssi: (2009). An optical MEMS sensor utilizing a chitosan film for catechol detection. Sensors and Actuators B, Vol 138 (2009), p.64–70.

DOI: 10.1016/j.snb.2009.01.065

Google Scholar

[6] A. Bouvree, M. Castro, Y. Grohens, and M. Rinaudo. Conductive Polymer nano-bioComposites (CPC): Chitosan-carbon nanoparticle a good candidate to design polar vapour sensors. sensors and actuators B, Vol 138 (2009), pp.138-147.

DOI: 10.1016/j.snb.2009.02.022

Google Scholar

[7] D. Feng, F. Wang, and Z. Chen: Electrochemical glucose sensor based on one step construction of gold nanoparticle-chitosan composite film. Sensors and Actuators B, Vol 138 (2009), pp.539-544.

DOI: 10.1016/j.snb.2009.02.048

Google Scholar

[8] B. Kumar, M. Castro, and J. Lu: Conductive bio Polymer nano-Composites (CPC): Chitosan-carbon nanotube transducers assembled via spray layer-by-layer for volatile organic compound sensing Talanta, Vol 81 (2010), p.908–915.

DOI: 10.1016/j.talanta.2010.01.036

Google Scholar

[9] R. Pauliukaite, M. E. Ghica, O. Fatibello-filho, and C. M. A: Electrochemical impedence studies of chitosan-modified electrodes for application in electrochemical sensors and biosensors, Electrochimica Acta, Vol 55 (2010), pp.6239-6247.

DOI: 10.1016/j.electacta.2009.09.055

Google Scholar

[10] W. Li, D. M. Jang, S. Y. An, D. Kim, S. -ku Hong, and H. Kim: Polyaniline–chitosan nanocomposite: High performance hydrogen sensor from new principle. Sensors and Actuators B, Vol 160 (2011), p.1020– 1025.

DOI: 10.1016/j.snb.2011.09.020

Google Scholar

[11] T. Ikhsan, I. Nainggolan, S. Derita, K. Rafezi, and Z. Arifin: The sensing mechanism and detection of low concentration acetone using chitosan-based sensors, Sensors and Actuators B, Vol 177 (2013), pp.522-528.

DOI: 10.1016/j.snb.2012.11.063

Google Scholar

[12] D. Du: (2007). One-step electrochemically deposited interface of chitosan–gold nanoparticles for acetylcholinesterase biosensor design. Journal of Electroanalytical Chemistry, Vol 605 (2007), p.53–60.

DOI: 10.1016/j.jelechem.2007.03.013

Google Scholar

[13] S. Yalçınkaya, C. Demetgül, M. Timur, and N. Çolak: (2010).

Google Scholar

[14] T. Advice, U. Kingdom, G. Long, and H. Canada, "Concise International Chemical Assessment Document 58, In Vitro, World Health Organization, Geneva (2004) pp.4-5.

Google Scholar

[15] D. K. Hore, D. S. Walker, L. Mackinnon, and G. L. Richmond: Molecular Structure of the Chloroform-Water and Dichloromethane-Water Interfaces. J. Phys. Chem. C 2007, Vol 111 (2007), pp.8832-8842.

DOI: 10.1021/jp067176t

Google Scholar

[16] T. Thanpitcha, A. Sirivat, A. M. Jamieson, and R. Rujiravanit: Preparation and characterization of polyaniline/chitosan blend film. Carbohydrate Polymers, Vol 64 (2006), pp.560-568.

DOI: 10.1016/j.carbpol.2005.11.026

Google Scholar

[17] R. Derrick Michele., Dusan Stulik., M. Landry , James: Infrared Spectroscopy in Conservation Science, Scientific tools for Conservation, The Getty Conservation Institute Los Angeles (1999) pp.93-98.

Google Scholar