Enhancing Sustainable Recycle Solid Waste to Porous Activated Carbon for Methane Uptake

Article Preview

Abstract:

Potential agro wastes (i.e palm kernel shell and coconut shell) for producing low cost activated carbon (AC) was investigated. In this study, the activated carbon was produced by carbonization, chemical impregnation with KOH and microwave irradiation. The pyrolysis was carried out at 700 °C in an inert environment for 2 h. Microwave activation was carried out at 400W for 6 minutes. Characteristics of the material were investigated using Fourier transform infrared spectroscopy (FT-IR) analysis and scanning electrode microscopy (SEM). Methane adsorption equilibrium data on the activated carbons produced were obtained using static volumetric method. Microwave palm shell activated carbon (MPAC) and microwave coconut shell activated carbon (MCAC) recorded highest methane uptake of 2.489 and 1.929 mmol/g at 3 bar, 30°C. The adsorption data were correlated with Langmuir and Freundlich isotherms. The results shows that microwave activated carbon from palm shell and coconut shell have good methane adsorption characteristics.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

19-23

Citation:

Online since:

December 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. Lee, H. Kang, W. Shim, C. Kim, and H. Moon: Methane Adsorption on Multi-Walled Carbon Nanotube at (303. 15, 313. 15, and 323. 15) K, J. Chem. Eng. Data, 51 (2006), 963-967.

DOI: 10.1021/je050467v

Google Scholar

[2] America Gas Association: US and Canadian Vehicle Market Analysis, 210, 1-63.

Google Scholar

[3] Aroua M.K., Wan Daud W. A., Yin C.Y., Adinata D: Adsorption capacities of carbon dioxide, oxygen, nitrogen and methane on carbon molecular basket derived from polyethyleneimine impregnation on microporous palm shell activated carbon, Separation and Purification Technology, 62 (2008).

DOI: 10.1016/j.seppur.2008.03.003

Google Scholar

[4] J.S. Sren´scek-Nazzal, W. Kamin´ska, B. Michalkiewicz, Z.C. Koren: Production, Characterization and Methane Storage Potential of KOH-Activated Carbon from Sugarcane Molasses, Ind. Crops and Prods. 47 (2013), 153– 159.

DOI: 10.1016/j.indcrop.2013.03.004

Google Scholar

[5] N.S. Nasri, U.D. Hamza, N.S. Ismail, M. M Ahmed and R. Mohsin: Assessment of Porous Carbons Derived from Sustainable Palm Solid Waste for Carbon Dioxide Capture, J of Cleaner Prod., 71 (2014), 148-157.

DOI: 10.1016/j.jclepro.2013.11.053

Google Scholar

[6] M. Delavar , A.A. Ghoreyshi , M. Jahanshahi and N. Nabian: Comparative experimental study of methane adsorption on multi-walled carbon nanotubes and granular activated carbons', Journal of Experimental Nanoscience, 9(3), (2014), 310-328.

DOI: 10.1080/17458080.2012.661470

Google Scholar

[7] S.A. Al-Muhtaseb, F.A. Abu Al-Rub, M. Al Zarooni: Adsorption equilibria of nitrogen, methane, and ethane on BDH-activated carbon, J. Chem. Eng. Data, 52, (2007), 60–65.

DOI: 10.1021/je060215+

Google Scholar