Characteristics of Nanostructured TiO2 Prepared by One-Step Soaking Method for Photovoltaic Application

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Nanostructured TiO2 films were prepared by a one-step soaking method, which has many advantages, such as simple fabrication, a short reaction time, and fast growth. We have investigated the growth of TiO2 films by the substrate orientation of the soaking method, which had an effect on the nanostructure of the TiO2 films. The TiO2 films prepared by this method had various structures: particulate-flat structure and sphere-flat structure. To determine the effect of the nanostructure of TiO2 films on the photovoltaic characteristics of solar cells, solar cell devices using the inorganic semiconductor Sb2S3 as a sensitizer were fabricated by chemical bath deposition (CBD). Our solar cell device, using TiO2 film with a sphere-flat structure as a photoelectrode, exhibited JSC, VOC, FF, and η values of 11.82 mA / cm2, 0.49 V, 30.27 %, and 1.74 %, respectively.

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December 2014

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Q. Zhan, W. Li, S. Liu, Controlled fabrication of nanosized TiO2 hollow sphere particles via acid catalytic hydrolysis/hydrothermal, Powder Technology, vol. 212 (2011) 145-150.

DOI: 10.1016/j.powtec.2011.05.004

Google Scholar

[2] H. Hu, H. Shen, C. Cui, D. Liang, P. Li, S. Xu, W. Tang, Preparation and photoelectrochemical properties of TiO2 hollow spheres embedded TiO2/CdS photoanodes for quantum-dot-sensitized solar cells, J. All. Comp., vol. 560 (2013) 1-5.

DOI: 10.1016/j.jallcom.2013.01.106

Google Scholar

[3] L. Feng, J. Jia, Y. Fang, X. Zhou, Y. Lin, TiO2 flowers and spheres for ionic liquid electrolytes based dye-sensitized solar cells, Electrochim. Acta., vol. 87 (2013) 629-636.

DOI: 10.1016/j.electacta.2012.09.037

Google Scholar

[4] I. G. Yu, Y. J. Kim, H. J. Kim, C. Lee, W. I. Lee, Size-dependent light-scattering of nanoporous TiO2 spheres in dye-sensitized solar cells, J. Mater. Chem., vol. 21 (2011) 532-538.

DOI: 10.1039/c0jm02606a

Google Scholar

[5] Y. J. Kim, M. H. Lee, H. J. Kim, G. Kim, Y. S. Choi, N. G. Park, K. Kim, W. I. Lee, Formation of highly efficient dye-sensitized solar cells by hierachical pore ceneration with nanoporous TiO2 spheres, Adv. Mater., vol. 21 (2009) 1-6.

DOI: 10.1002/adma.200900294

Google Scholar

[6] P. P. Boix, Y. H. Lee, F. F. Santiago, S. H. Im, I. M. Sero, J. Bisquert, S. I. Seok, From flat to nanostructured photovoltacis-balance between thickness of the absorber and charge screening in sensitized solar cells, ACS Nano, vol. 6 (2012).

DOI: 10.1021/nn204382k

Google Scholar

[7] U. Bach, D. Lupo, P. Comte, J. E. Moser, F. Weissortel, J. Salbeck, H. Spreitzer, M. Gratzel, Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies, Nature, vol. 395 (1998) 583-585.

DOI: 10.1038/26936

Google Scholar

[8] M. Wang, J. Liu, N. L. C. Ha, S. J. Moon, P. Liska, R. H. Baker, J. E. Moser, G. Gratzel, P. Wang, S. M. Zakeeruddin, M. Gratzel, High efficiency solid-state sensitized heterojunction photovoltaic device, Nanotoday, vol. 5 (2010) 169-174.

DOI: 10.1016/j.nantod.2010.04.001

Google Scholar

[9] H. Wedemeyer, J. Michels, R. Chmielowski, S. Bourdais, T. Muto, M. Sugiura, J. Bachmann, Nanocrystalline solar cells with an antimony sulfide solid absrober by atomic layer deposition, Energy Environ. Sci. The Royal Society of Chemistry (2012).

DOI: 10.1039/c2ee23205g

Google Scholar

[10] Y. Itzhaik, O. Niitsoo, M. Page, G. Hodes, Sb2S3-Sensitized nanoporous TiO2 solar cell, J. Phys. Chem. C, vol. 113 (2009) 4254-4256.

DOI: 10.1021/jp900302b

Google Scholar

[11] S. H. Im, H. J. Kim, J. H. Rhee, C. S. Lim, S. I. Seok, Performance improvement of Sb2S3-sensitized solar cell by introducing hole buffer layer in cobalt complex electrolyte, Energy Environ. Sci., vol. 4 (2011) 2799-2802.

DOI: 10.1039/c0ee00741b

Google Scholar