The Production, Qualitative and Adsorbent Study of β-Cyclodextrin Molecular Engram

Article Preview

Abstract:

In the paper, the molecular engram polymer is produced by dithizone which is functional monomer,β-cyclodextrin which is pore-forming material and chloroepoxy propane which is crosslinking agent. Atomic absorption method is used to study its adsorption for lead. Thermodynamic model of adsorption and dynamic reaction order are discussed. The results show that adsorption is endoergic process and accords with Freundlich isothermal adsorption equation. Adsorption system conforms with pseudo-second order dynamic model, the static saturation adsorption amount is 45.55mg/g.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

2958-2961

Citation:

Online since:

January 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S.H. Yang , Z.X. Qu and H.X. Wang: The migration and accumulation of lead in rice and its influence on the growth and development of rice, Acta Ecol Sin, 1986, 6(4), 312~323.

Google Scholar

[2] Otero-RomaníJ, Moreda-Pi and P. Bermejo-Barrera: Synthesis, characterization and evaluation of ionic-imprinted polymers for solid-phase extraction of nickel from seawater, Anal Chim Acta, 2008, 630(17), 1~9.

DOI: 10.1016/j.aca.2008.09.049

Google Scholar

[3] N. Candan, N. Tüzmen and M. Andac: Cadmium removal out of human plasma using ion-imprinted beads in a magnetic column, Mater Sci Eng C, 2008, 29(1, 1[F8]): 144~152.

DOI: 10.1016/j.msec.2008.06.002

Google Scholar

[4] P. Metilda, K, Prasad and Kala: Ion imprinted polymer based sensor for monitoring toxic uranium in environmental samples, Anal Chim Acta, 2007, 582 (1): 147~153.

DOI: 10.1016/j.aca.2006.08.052

Google Scholar

[5] D. Sobhi, Prabhakara, P. Rao, Prasada and T. Rao: Investigation of different polymerization methods on the analytical performance of palladium ion imprinted polymer materials, Anal ChimActa 2005, 536(1-2), 197~206.

DOI: 10.1016/j.aca.2004.12.052

Google Scholar

[6] B.E. Wang, Y.Y. Hu, L. Xie: CMC immobilized aspergillus inactivated smoke ball the adsorption mechanism of reactive brilliant blue KN - R - adsorption equilibrium, kinetics, dynamics and diffusion and mass transfer process, Journal of Environmental Sciences, 2008, 28(1), 89~94.

Google Scholar

[7] H. Asanuma, M. Kakazu, M. Shibata: 'Synthesis molecularly imprinted polymer of β-cyclodextrin for the efficient recognition of cholesterol. Supramolecular Seienee. 1998, 5(3-4): 417~421.

DOI: 10.1016/s0968-5677(98)00042-x

Google Scholar