Synthesis of Nitro-Functionalized A3B-Type Tetraphenylporphyrins Compounds and Potential Applications in Dye-Sensitized Solar Cells

Hui Li; Yuan Bin She; Hai Yan Fu; Ting Wen Jia

doi:10.4028/www.scientific.net/AMM.748.21

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 748Synthesis of Nitro-Functionalized A3B-Type...

Synthesis of Nitro-Functionalized A₃B-Type Tetraphenylporphyrins Compounds and Potential Applications in Dye-Sensitized Solar Cells

Abstract:

An improved Adler pre-mixed method based on a TFA-catalyzed condensation reaction between aldehydes and pyrroles was developed to synthesize a series of nitro-functionalized A₃B-type tetraphenylporphyrins, and all the structures of A₃B-type tetraphenylporphyrins were characterized by melting point analysis, electronic absorption spectroscopy, infrared spectroscopy, high-resolution mass spectroscopy, ¹H NMR spectroscopy, and elemental analysis. Several factors in the synthesis process were systematically investigated to establish the optimum reaction conditions, hereby obtaining the high yield of products.

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Applied Mechanics and Materials (Volume 748)

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21-24

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https://doi.org/10.4028/www.scientific.net/AMM.748.21

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Online since:

April 2015

Authors:

Hui Li, Yuan Bin She*, Hai Yan Fu, Ting Wen Jia

Keywords:

A₃B-Type Porphyrin, Characterization, Dye-Sensitized Solar Cells, Synthesis

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