Hydrothermal Synthesis and Hydrophilic Performance of Silica Modified Titanium Surfaces

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Abstract:

It is well known that titanium (Ti) has excellent properties of anticorrosion, biocompatibility and low modulus that would be applied in many clinical applications. The aim of this study wants to increase the hydrophilicity of titanium surface through silanization and then grafted with hydroxyapatite (HA) by hydrothermal synthesis method. Physiochemical analysis of grafting plate substrate was observed by attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR), scanning electron microscopy (SEM), and contact angle analysis. The surfaces with silanization were strongly interaction between SiO2 and TiO2, and thus Ti-O-Si-bonds formed having larger surface areas but only showed a little improved hydrophilicity. The hydrophilicity of Ti substrate was largely increased after the hydrothermal process. Compared with Ti surface without any surface treatment, the surface which modified with hydrothermal synthesis can improve the wettability of Ti surfaces. Furthermore, the Ti surface through silanized modification before hydrothermal synthesis held good calcium phosphate precipitates existing due to the better calcium ion combined ability with polar bond of aldehyde group (Ti-O-Si-CO-).

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449-452

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April 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] B. Karahalil, E. Kadioglu, A.M. Tuzuner-Oncul, E. Cimenc, E. Emercea, R.S. Kisnisci, Micronucleus assay assessment of possible genotoxic effects in patients treated with titanium alloy endosseous implants or miniplates, Mutat. Res. Genet. Toxicol. Environ. Mutagen. 760 (2014).

DOI: 10.1016/j.toxlet.2010.03.557

Google Scholar

[2] J. Du, X. Liu, D. He, P. Liu, F. Ma, Q. Li, Influence of Alkali Treatment on Ti6Al4V Alloy and the HA Coating Deposited by Hydrothermal-Electrochemical Methods, Rare. Met. Mater. Eng. 43 (2014) 830-835.

DOI: 10.1016/s1875-5372(14)60093-x

Google Scholar

[3] T. Onoki, T. Hashida, New method for hydroxyapatite coating of titanium by the hydrothermal hot isostatic pressing technique, Surf. Coat. Technol. 200 (2006) 6801-6807.

DOI: 10.1016/j.surfcoat.2005.10.016

Google Scholar

[4] L.L. Hench, Bioceramics: from concept to clinic, J. Am. Ceram. Soc. 74 (1991) 1487-1510.

Google Scholar

[5] W.C. Chen, C.L. Ko, H.N. Kuo, D.J. Lin, H.Y. Wu, Y. Lo, C.W. Lou, J.H. Lin, Mineralization of Progenitor Cells with Different Implant Topographies, Procedia. Eng. 36 (2012) 173-178.

DOI: 10.1016/j.proeng.2012.03.027

Google Scholar

[6] W.C. Chen, C.L. Ko, H.Y. Wu, P.L. Lai, C.J. Shih, Thermal cycling effects on adhesion of resin-bovine enamel junction among different composite resins, J. Mech. Behav. Biomed. Mater. 38 (2014) 105-113.

DOI: 10.1016/j.jmbbm.2014.07.003

Google Scholar

[7] M.M. Karabela, I.D. Sideridou, Effect of the structure of silane coupling agent on sorption characteristics of solvents by dental resin-nanocomposites, Dent. Mater. 24 (2008) 1631-1639.

DOI: 10.1016/j.dental.2008.02.021

Google Scholar

[8] Y. Xie, C.A.S. Hill, Z. Xiao, H. Militz, C. Mai, Silane coupling agents used for natural fiber/polymer composites: a review, Compos. Part. A . Appl. Sci. Manuf. 41 (2010) 806-819.

DOI: 10.1016/j.compositesa.2010.03.005

Google Scholar

[9] W.C. Chen, C.L. Ko, Roughened titanium surfaces with silane and further RGD peptide modification in vitro, Mater. Sci. Eng. C. 33 (2013) 2713-2722.

DOI: 10.1016/j.msec.2013.02.040

Google Scholar