Assumed Mechanism of Polymeric Deposit Formation in Recycle Propylene Washing Column during Bulk Polymerization

Edward Mayer; Alla Trofimova; Vasiliy Mashukov; Alexey Pestryakov

doi:10.4028/www.scientific.net/AMM.756.179

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 756Assumed Mechanism of Polymeric Deposit Formation...

Assumed Mechanism of Polymeric Deposit Formation in Recycle Propylene Washing Column during Bulk Polymerization

Abstract:

This study presents the results of polymeric deposit analysis from propylene washing column of «Spheripol» process polymerization unit using such methods as gel-permation chromatography, differential scanning calorimetry (DSC), X-ray phase analysis, IR and NMR¹³C-spectroscopy and analytical process control methods. For comparison the relative data for larger volume polypropylene grades have been presented as well. Based on the findings and available similar practice in a slurry process an assumed formation mechanism was proposed for the discussion.

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Periodical:

Applied Mechanics and Materials (Volume 756)

Pages:

179-186

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.756.179

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Online since:

April 2015

Authors:

Edward Mayer, Alla Trofimova, Vasiliy Mashukov, Alexey Pestryakov*

Keywords:

Bulk Polymeri Z Ation, Polymeric Deposits, Polypropylene, Potential Reasons

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* - Corresponding Author

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