Detection of Sodium Ions by SPR Sensor Using Modified Self-Assembled Calix[4]Arene Deravative Monolayer

Abstract:

A new SPR sensor surface based onself-assembled-Calix [4] arene-derivative-monolayer was proposed for the detection of sodium in water. The immobisation of claixarene onto the gold surface was confirmed by impedance spectroscopy (EIS). Three alkaliions were used K⁺, Na⁺ and Ca²⁺ and the influence of pH on ions detection was studied and optimized. The Calix [4] arene-gold SPR sensor developed was characterized by low limit of detection (LOD) for about 10^-10 M, high sensitivity and wide linear detection range between 10^-6M and 10^-14M.

• Periodical: Applied Mechanics and Materials (Volumes 799-800)
• Pages: 915-918
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.799-800.915
• Online since: October 2015
• Authors: M. Benounis*, Nicole Jaffrezic-Renault, Isabelle Bonnamour, Nadhir Messai
• Keywords: Calixarene, Cysteamine, Self-Assembled Monolayer, Sodium, Surface Plasmon Resonance Sensor, Surface-Modified Gold

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