Water/Alcohol Soluble Poly(3-Alkylthiophene) Derivative Self-Assembly with Fullerene Derivative via Hydrogen Bonding

Yi Chiang Huang; Hsu Feng Lee; Po Hsun Wang; Pei Chen Huang; Jue Houng Lin; Yu Chao Tseng; Yu Kai Han; Wen Yao Huang

doi:10.4028/www.scientific.net/AMR.1051.303

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1051Water/Alcohol Soluble Poly(3-Alkylthiophene)...

Water/Alcohol Soluble Poly(3-Alkylthiophene) Derivative Self-Assembly with Fullerene Derivative via Hydrogen Bonding

Abstract:

In this research, a regioregular poly (3-alkylthiophene) derivative had been synthesized via the post-polymerization functionalization, poly (3-hexylamine thiophene), which are soluble in water and water miscible solvents such as methanol, DMSO. The suitable energy level, good thermal stability and water/alcohol solubility of polymers which promising applied in polymer solar cells and processed by water or environmental-friendly solvents. In blend of functionalization polymers and fullerene derivative potassium [6,6]-phenyl-C₆₁-butyrate shows significant UV absorption decay phenomenon and occur precipitates follow with time increase. To further investigate the mechanism of composite, FT-IR analysis and TEM investigate were used, the polymer would be bonded with carboxyl of fullerene derivative via hydrogen bonding in the carboxyl region and TEM images demonstration the mixture that be able to self-assembly a interpenetrating network composite.

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Periodical:

Advanced Materials Research (Volume 1051)

Pages:

303-307

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1051.303

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Online since:

October 2014

Authors:

Yi Chiang Huang, Hsu Feng Lee, Po Hsun Wang, Pei Chen Huang, Jue Houng Lin, Yu Chao Tseng, Yu Kai Han, Wen Yao Huang*

Keywords:

Alkylthiophene, Hydrogen Bonding, Self-Assembly, Water/Alcohol Soluble

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* - Corresponding Author

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