First-Order Phase Transition and Magnetocaloric Effect of MnFeP0.63Ge0.12Si0.25 Compound

Article Preview

Abstract:

In this paper, the magnetic phase transition and magnetocaloric effect have been investigated in the Fe2P-type MnFeP0.63Ge0.12Si0.25 compound. The X-ray diffraction patterns measured at different temperatures indicate that the crystal structure remains and the lattice parameters change sharply near the transition temperature when a phase transition takes place. The isofield magnetization curves on heating and cooling and the Arrott plots reveal that the nature of the transition is first order. The characteristic of giant magnetocaloric effect results from the field-induced first-order metamagnetic phase transition, which makes the compound having potential applications in magnetic refrigeration.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

37-40

Citation:

Online since:

October 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] K.A. Gschneidner Jr., V.K. Pecharsky and A.O. Tsokol: Rep. Prog. Phys., Vol. 68 (2005), p.1479.

Google Scholar

[2] E. Brück: J. Phys. D: Appl. Phys., Vol. 38 (2005), p. R381.

Google Scholar

[3] M.H. Phana and S.C. Yu: J. Magn. Magn. Mater., Vol. 308 (2007), p.325.

Google Scholar

[4] A. Planes, L. Mañosa and M. Acet: J. Phys.: Condens. Matter, Vol. 21 (2009), p.233201.

Google Scholar

[5] V.K. Pecharsky and K.A. Gschneidner Jr.: Phys. Rev. Lett., Vol. 78 (1997), p.4494.

Google Scholar

[6] O. Tegus, E. Brück, K.H.J. Buschow and F.R. de-Boer: Nature, Vol. 415 (2002), p.150.

Google Scholar

[7] D.T. Cam Thanh, E. Brück, O. Tegus, J.C.P. Klaasse, T.J. Gortenmulder and K.H.J. Buschow: J. Appl. Phys., Vol. 99 (2006), p. 08Q107.

DOI: 10.1063/1.2170589

Google Scholar

[8] D.T. Cam Thanh, E. Brück, N.T. Trung, J.C.P. Klaasse and K.H.J. Buschow: J. Appl. Phys., Vol. 103 (2008), p. 07B318.

Google Scholar

[9] L. Song, G.F. Wang, Z.Q. Ou, O. Haschaolu, O. Tegus, E. Brück and K.H.J. Buschow: J. Alloys. Compds., Vol. 474 (2009), p.388.

DOI: 10.1016/j.jallcom.2008.06.098

Google Scholar

[10] G.F. Wang, Z.R. Zhao, L. Song and O. Tegus: J. Alloys. Compds., Vol. 554 (2013), p.208.

Google Scholar

[11] L. Zhang: Unusual Magnetic Behavior of Some Rare-Earth and Manganese Compounds (Ph.D., Universiteit van Amsterdam, the Netherlands 2003), p.119.

Google Scholar

[12] G.F. Wang: Magnetic and Calorimetric Study of the Magnetocaloric Effect in Intermetallics Exhibiting First-order Magnetostructural Transitions (Ph.D., Universidad de Zaragoza, Spain, 2012), p.212.

Google Scholar

[13] B.K. Banerjee: Phys. Lett., Vol. 12 (1964), p.16.

Google Scholar

[14] S. Yu. Dan'kov, A.M. Tishin, V.K. Pecharsky and K.A. Gschneidner Jr.: Phys. Rev. B, Vol. 57 (1998), p.3478.

Google Scholar