Electrical and Optical Stability of Two Kinds of Different Element Doped Tin Oxide Film Carrier Materials in an Acid Environment

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The stability of the fluorine doped tin oxide (FTO) and the indium doped tin oxide (ITO) films, which are used as gene chip carrier, are detected in an acid solution. The change of relative resistivity (Δ R/R) with immersion time and average visible light transmittance of the films are contrasted before and after immersing in 1 mol/L (1M) H2SO4 solution. The results indicate that the Δ R/R of ITO film sample increases rapidly with increasing the immersion time, and Δ R/R is 111% after 12 h;However, the Δ R/R of FTO film sample increases smoothly and the Δ R/R is 2.9% after 100 h immersion. At the same time, the average visible light transmittance of FTO film decreased, but ITO film is completely corroded, and the average visible light transmittance is close to the glass transmittance. The potentiodynamic polarization curves show that the corrosion current of FTO film is 1.749 × 106A and less than ITO,so the corrosion resistance of FTO film is higher than ITO film in 1M H2SO4 solution. Moreover, the corrosion morphology validates this conclusion.

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236-239

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November 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] F. K. Shan, G. X. Liu, W. J. Lee, Structural, optical and electrical properties of transparent conductive In2O3-doped ZnO thin fims grown by pulsed laser deposition, Journal of the Korean Physical Society. 50(3)(2007) 629-631.

DOI: 10.3938/jkps.50.626

Google Scholar

[2] J. H. Bae, J .M. Moon, J .W. Kang, Transparent, low resistance, and flexible amorphous ZnO-doped In203 anode grown on a PES substrate, Jounral of the Electrochemical Society. 154 (3)(2007)J81-J85.

DOI: 10.1149/1.2426800

Google Scholar

[3] J. Xu, J. Zhu, Q. Huang, A novel DNA-modified indium tin oxide electrode, Electrochemistry Communications. 3(2001)665-669.

DOI: 10.1016/s1388-2481(01)00245-4

Google Scholar

[4] V. Stambouli, M. Labeau, I. Matko, Development and functionalisation of Sb doped SnO2 thin films for DNA biochipapplications, Sensors and Actuators B: Chemical. 113(2006)1025-1033.

DOI: 10.1016/j.snb.2005.03.108

Google Scholar

[5] J .H. Lee, S. Y. Lee , B .O. Park , Fabrication and characteristics of transparent conducting In2O3-ZnO thin films by ultrasonic spray pyrolysis, Materials Science and Engineering: B. 127(2006)267-271.

DOI: 10.1016/j.mseb.2005.10.008

Google Scholar

[6] M. Miyakawa, K. Ueda , H. Hosono, Carrier control in transparent semiconducting oxide thin films by ion implantation: MgIn2O4 and ZnO, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 191(2002).

DOI: 10.1016/s0168-583x(02)00550-5

Google Scholar

[7] N. Sonoyama, K. Kawamura, A. Yamada, Electrochemical luminescence of rare earth metal ion doped MgIn2O4 electrodes, Journal of the Electrochemical Society. 153(3)(2006)45-50.

DOI: 10.1149/1.2158574

Google Scholar