New Catalysts of Methanol Oxidation into Formaldehyde

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Abstract:

The results of methanol oxidation to formaldehyde at the presence of iron-molybdenum catalyst fixed on silicate matrix are introduced for the first time. The elaborated catalyst is stable through time and does not depend on the methanol content at input in the learnt interval of temperatures (270-400oC). СН2О output fluctuates from 94.8 to 98.2% at selectivity on formaldehyde from 97.3 to 100%.

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Advanced Materials Research (Volumes 1079-1080)

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37-41

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December 2014

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] N.V. Abramov, A.M. Golovachev, A.I. Zayats, B.N. Starshinov, Z. Ya. Fedoseeva, V.E. Pastor, patent № 2072979 (1997).

Google Scholar

[2] B.I. Popov, N.G. Skomorohova, V.S. Babkin, V.A. Bunev, G.K. Boreskov, The methanol oxidation in the presence of aliphatic hydrocarbons on iron-molibdenic and chrome-iron-molibdenic catalysts, Kinetics and catalysis. 25, 4 (1984) 856-861.

Google Scholar

[3] N.V. Nikolenko, A.O. Kostynyuk, The low-temperature adsorptive properties of iron-molybdenic catalyst of the methanol conversion, Questions of chemistry and chemical technology. 4 (2009) 220-225.

Google Scholar

[4] M.P. House, A.F. Carley, R. Echeverria-Valda, M. Bowker, Effect of Varying the Cation Ratio within Iron Molybdate Catalysts for the Selective Oxidation of Methanol, J. phys. Chem. C. 112, 11 (2008) 4333-4341.

DOI: 10.1021/jp711251b

Google Scholar

[5] A.P. Ilyin, A.A. Ilyin, A.B. Zhukov, R.N. Rumyantsev, RF patent № 2458738 (2012).

Google Scholar

[6] К. Gyukkel, К. Vanninger, М. Estenfelder, К. Fisher, U. Dyurr, RF patent № 2393014 (2010).

Google Scholar

[7] V.N. Bibin, B.I. Popov, Kinetics of methanol oxidation by air on the oxidic iron-molibdenic catalyst, Kinetics and catalysis. 10, 6 (1969) 1326-1335.

Google Scholar