Radical Polymerization of a Novel Methacrylamide Derivative

Chao Yuan; Ping Liu; Long Hua Chen; Yuan Zhang

doi:10.4028/www.scientific.net/AMR.1095.359

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Preparation of Zeolite from Waterworks Sludge for Ammonium Ion Removal in Wastewater
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Simulation Study of the Volume Properties and Diffusion of 1-Butyl-3-Methylimidazolium Tetrafluoroborate/Ethanol Mixture
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Synthesis and Application of the Three-Component Lyotropic Liquid Crystal
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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1095Radical Polymerization of a Novel Methacrylamide...

Radical Polymerization of a Novel Methacrylamide Derivative

Abstract:

The radical polymerization of a novel methacrylamide derivative, N-[o-(4-ethyl-4, 5-dihydro-1, 3-oxazol-2-yl) phenyl] methacrylamide ((S)-EtOPMAM), was carried out to obtained optically active polymers. The polymer yield and the chiroptical behavior of the resultant polymers have been examined in detail by using IR and ¹H NMR spectroscopies in comparison with our previous observation. The polymers showed relatively high molecular weights (Mn=8000-16000) and largest specific rotations ([α]₂₅^D =+120.6^o). Particularly, the largest specific optical rotation of the polymer is almost the six times of the monomer.

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Advanced Materials Research (Volume 1095)

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359-362

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1095.359

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Online since:

March 2015

Authors:

Chao Yuan, Ping Liu, Long Hua Chen, Yuan Zhang*

Keywords:

Methacrylamide, Optical Activity, Oxazoline, Radical Polymerization

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