Use of Graphene Oxide as a Bitumen Modifier: An Innovative Process Optimization Study

Article Preview

Abstract:

Graphene because of its higher surface area, strength, thinness and high electric conductivity has diversified uses from mechanical, electrical to bio medical engineering. This paper presents an initial study on modifying 80/100 penetration grade bitumen with Graphite oxide (GO) prepared by using Simplified Room Temperature Hummer’s process. The concept of utilizing GO for modification is adopted in order to improve the stiffness of the binder which can be helpful in reducing rutting potential of the pavement and to have electro thermal conductivity in modified binder, thus can be used during pavement remediation work. The limited trial rheological results obtained for 0.1125 wt. % GO modified bitumen and 0.225 wt. % GO modified bitumen showed that modification of bitumen with GO has improved its elastic capacity at higher temperature and lower frequency regime thus successfully can be used as bitumen modifier in future.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

365-369

Citation:

Online since:

May 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] The Bitumen Industry – A Global Perspective, Second Edition. (Asphalt Institute Publishing, USA 2011).

Google Scholar

[2] World Asphalt: Industry Study with Forecasts for 2013 & 2018, The Freedonia Group2010.M. A.

Google Scholar

[3] Lee, C., Wei, X., Kysar, J.W. & Hone, J. Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene. Science, 321(5887), 385-8 (2008).

DOI: 10.1126/science.1157996

Google Scholar

[4] Kuilla, T., Bhadra, S., Yao, D., Kim, N.H., Bose, S. & Lee, J. H in Recent Advantages in graphene based polymer composites. Polym Science, 35(11), 1350-75 (2010).

DOI: 10.1016/j.progpolymsci.2010.07.005

Google Scholar

[5] Shenghua, L., Yujuan, M., Chaochao, Q., Ting, S., Jingjing, L. & Qingfang, Z. Effect of graphene oxide nanosheets of microstructure and mechanical properties of cement composites. Construction and Building Material , Vol 49, pp.121-127 (2013).

DOI: 10.1016/j.conbuildmat.2013.08.022

Google Scholar

[6] Geim, A.K. Graphene: Status and Prospects in Science, Vol 324 no. 5934, pp.1530-1534 (2009).

DOI: 10.1126/science.1158877

Google Scholar

[7] J.R. Potts, D.R. Dreyer, C. Bielawski, R.S. Ruoff Graphene-based polymer nanocomposites in Polymer, 52, p.5 – 25 (2011).

DOI: 10.1016/j.polymer.2010.11.042

Google Scholar

[8] T. Kuila, S. Bose, C.E. Hong, P. Khanra, N.H. Kim, J.H. Lee Preparation of functionalized graphene/linear low density polyethylene composites by a solution mixing method in Carbon 49, p.1033 – 1037(2011).

DOI: 10.1016/j.carbon.2010.10.031

Google Scholar

[9] Y.W. Zhu, S. Murali, W.W. Cai, X.S. Li, J.W. Suk, J.R. Potts, et al. Graphene and graphene oxide: synthesis, properties and applications in Adv Mater, 22, p.3906–3924, (2010).

DOI: 10.1002/adma.201001068

Google Scholar

[10] W.S. Hummers, R.E. Offeman Preparation of graphite oxide in J Am Chem Soc, 80 (1958), p.1339–1348.

Google Scholar

[11] Ling Fu, Hongbo Liu Technology research on oxidative degree of graphite oxide prepared by Hummers method in Carbon (4), p.10–12 (2005).

Google Scholar

[12] Huang, N.M., Lim, H.N., Chia, C.H., Yarmo, M.A. and Muhamad, M.R. Simple room-temperature preparation of high-yield large-area graphene oxide. International Journal of Nano medicine, 6 pp.3443-3448 (2011).

DOI: 10.2147/ijn.s26812

Google Scholar

[13] Ban, F.Y., Majid, S.R., Huang, N.M. and Lim, H.N., Graphene Oxide and Its Electrochemical Performance. International Journal of Electrochemical Science, 7, pp.4345-4351 (2012).

DOI: 10.1016/s1452-3981(23)19543-5

Google Scholar

[14] Mturi, G.A.J.; O'Connell, J.; Zoorob, SE Investigating the Rheological characteristics of South African road bitumens Paper presented at the 29th Annual Southern African Transport Conference 16 - 19 August 2010 Walk Together, CSIR International Convention Centre, Pretoria, South Africa.

Google Scholar