Effect of Molecular Weight on Morphological Structure of Electrospun PVA Nanofibre

Article Preview

Abstract:

This work focuses on the preparation of electrospun Polyvinyl Alcohol (PVA) nanofibres of three different molecular weights. The electrospinning process parameters were varied in terms of the voltage and feed rate. Scanning Electron Microscopy technique was used to characterize the morphological structure of the electrospun PVA nanofibre. The results show that the average fibre diameter increased as the molecular weight of the polymer increased. The formation of beads occurs from the lowest molecular weight sample of 89K However, long, continuous and beaded-free fibres were obtained from the 125K and 205K polymer weight PVA. The results also suggest that higher spinning voltage and feed rate produce larger fibre diameter, respectively.Keywords : Polyvinyl Alcohol, nanofibres, molecular weight, electrospinningCorresponding Author:Khairunnadim Ahmad Sekak, Faculty of Applied Sciences, Universiti Teknologi MARA (UiTM), Shah Alam, 40450 Selangor Darul Ehsan.Email: nadim821@salam.uitm.edu.my

You might also be interested in these eBooks

Info:

Periodical:

Pages:

203-208

Citation:

Online since:

December 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] T. Subbiah, G. Bhat, R. Tock, , S., Parameswaran, & S. Ramkumar, Electrospinning of nanofibers. Journal of Applied Polymer Science, 96(2), (2005). 557-569.

DOI: 10.1002/app.21481

Google Scholar

[2] A. Frenot, & I.S. Chronakis, Polymer nanofibers assembled by electrospinning. Current opinion in colloid & interface science, 8(1), (2003). 64-75.

DOI: 10.1016/s1359-0294(03)00004-9

Google Scholar

[3] R. Barhate, C. Loong, and S. Ramakrishna, Preparation and characterization of nanofibrous filtering media, Journal of Membrane Science, 283, (2006). 209-218.

DOI: 10.1016/j.memsci.2006.06.030

Google Scholar

[4] S. Tan, X. Huang, & B. Wu, Some fascinating phenomena in electrospinning processes and applications of electrospun nanofibers. Polymer International, 56(11), (2007). 1330-1339.

DOI: 10.1002/pi.2354

Google Scholar

[5] C. Feng, K. Khulbe, & T. Matsuura, Recent progress in the preparation, characterization, and applications of nanofibers and nanofiber membranes via electrospinning/interfacial polymerization. Journal of Applied Polymer Science, 115(2), (2010).

DOI: 10.1002/app.31059

Google Scholar

[6] S. Ramakrishna, K. Fujihara, W. Teo, T. Lim, and Z. Ma, An introduction to electrospinning and nanofibers, World Scientific Singapore. (2005).

Google Scholar

[7] A.P. S Sawhney, B. Condon, K. V Singh, S. S Pang, G. Li, D. Hui, Modern applications of nanotechnology in textile, Textile Research Journal, 78(8) (2008). 731-739.

DOI: 10.1177/0040517508091066

Google Scholar

[8] T. Subbiah, G. S Bhat, R. W Tock, S. Parameswaran, S. Ramkumar, Electrospinning of nanofibers" Journal of Applied Polymer Science, 96(2) (2005). 557-569.

DOI: 10.1002/app.21481

Google Scholar

[9] O.O. Dosunmu, G.G. Chase, J. Varabhas, W. Kataphinan, and D. Reneker, Polymer nanofibers from multiple jets produced on a porous surface by electrospinning. Nanotechnology, 17(4) (2006). 1123-1127.

DOI: 10.1088/0957-4484/17/4/046

Google Scholar

[10] D.H. Reneker, A.L. Yarin, H. Fong, and S. Koombhongse, Bending instability of electrically charged liquid jets of polymer solutions in electrospinning, Journal of Applied Physics, 87(9), (2000). 4531.

DOI: 10.1063/1.373532

Google Scholar

[11] N. Bhardwaj and S. C. Kundu, Electrospinning : A fascinating fiber fabrication technique, 28, (2010). 325–347.

DOI: 10.1016/j.biotechadv.2010.01.004

Google Scholar

[12] B. D. Li and Y. Xia, Electrospinning of nanofibers: reinventing the wheel?, 14 (2004). 1151–1170.

DOI: 10.1002/adma.200400719

Google Scholar

[13] N.A.A. Shukry, K.A. Sekak, M.R. Ahmad, and T. J. B. Effendi, Proceedings of the International Colloquium in Textile Engineering, Fashion, Apparel and Design 2014 (ICTEFAD 2014), (2014). 7–11.

DOI: 10.1007/978-981-287-011-7_2

Google Scholar

[14] N.D. Nor Affandi, M.R. Ahmad, A. Baharudin, and N.A. Abdullah Shukry, Effect of crosslinking on the solubility and morphological structures of the PVA nanofibres, 2012 IEEE Colloquium on Humanities, Science and Engineering, (2012). 458–462.

DOI: 10.1109/chuser.2012.6504358

Google Scholar

[15] P. Lu, & B. Ding, Applications of electrospun fibers. Recent patents on nanotechnology, 2(3), (2008). 169-182.

DOI: 10.2174/187221008786369688

Google Scholar

[16] P. Supaphol and S. Chuangchote, On the electrospinning of poly(vinyl alcohol) nanofiber materials: a revisit, 108(2) (2008). 969–978.

DOI: 10.1002/app.27664

Google Scholar

[17] Y. Wu, J.Y. Yu & C. Ma. Electrospun nanoporous fiber. Textile Research Journal, 78 (2008). 812-815.

DOI: 10.1177/0040517507090550

Google Scholar

[18] C. Zhang and X. Yuan, Study on morphology of electrospun poly (vinyl alcohol ) mats, European Polymer, 41 (2005). 423–432.

DOI: 10.1016/j.eurpolymj.2004.10.027

Google Scholar

[19] P. Zahedi, I. Rezaeian, S.H. Jafari and Z. Karami, Preparation and release properties of electrospun poly(vinyl alcohol)/ poly(ε-caprolactone) hybrid nanofibers : optimization of process parameters via d-optimal design method, Macromolecular Research, 21(6) (2013).

DOI: 10.1007/s13233-013-1064-z

Google Scholar

[20] C.J. Thompson, G.G. Chase, A.L. Yarin, and D.H. Reneker, Effects of parameters on nanofiber diameter determined from electrospinning model, Polymer, 48(23) (2007). 6913–6922.

DOI: 10.1016/j.polymer.2007.09.017

Google Scholar

[21] Q.P. Pham, U. Sharma, and A.G. Mikos, Electrospinning of polymeric nanofibers for tissue engineering applications: a review, Tissue Engineering, 12(5), (2006). 1197-211.

DOI: 10.1089/ten.2006.12.1197

Google Scholar

[22] P. Gupta, C. Elkins, T.E. Long and G.L. Wilkes, Electrospinning of linear homopolymer of polymer (methyl methacrylate): exploring relationships between fiber formation, viscosity, molecular weight and concentration in good solvent. Polymer 46, (2005).

DOI: 10.1016/j.polymer.2005.04.021

Google Scholar

[23] H. Chen and Y.L. Hsieh. Ultrafine hydrogel fiber with dual temperature and p-H responsive swelling behaviour. Journal of Polymer Science Part A: Polymer Chemistry, 42(24) (2004). 6331–6339.

DOI: 10.1002/pola.20461

Google Scholar

[24] B. Huan, C.H. Dong, X. Y Yuan and K. D Yao. Electrospinning of chitosan solutions in acetic acid with poly(ethylene oxide) Journal of Biometerial Science Polymer. 15, (2004). 797.

DOI: 10.1163/156856204774196171

Google Scholar

[25] C. Mit-Uppatham, M. Nithitanakul and P. Supaphol, Ultrafine electrospun polyamide-6 fibers: effect of solution conditions on morphology and average diameter. Macromol Chem. Phys 205, (2004). 2327.

DOI: 10.1002/macp.200400225

Google Scholar

[26] S. Ramakrishna, An introduction to electrospinning and nanofibers, World Scientific Pub Co Inc. (2005).

Google Scholar

[27] B. Ding, H. Kim, S. Lee, D. Lee, and K. Choi, Preparation and Characterization of Nanoscaled Poly ( vinyl alcohol ) Fibers via Electrospinning, 3(2) (2002). 73–79.

DOI: 10.1007/bf02875403

Google Scholar

[28] X.Y. Geng, O.H. Kwon and J.H. Jang. Electrospinning of Chitosan dissolved in concentrated acetic acid solution. Biomaterials 26 (2005). 5427.

DOI: 10.1016/j.biomaterials.2005.01.066

Google Scholar

[29] J. M. Deitzel, J. D. Kleinmeyer, J. K. Hirvonen, and N. C. Beck Tan, Controlled deposition of electrospun poly(ethylene oxide) fibers, Polymer (Guildf)., 42 (2001). 8163–8170.

DOI: 10.1016/s0032-3861(01)00336-6

Google Scholar

[30] E. Adomavičiūtė, The influence of applied voltage on poly(vinyl alcohol) nanofibre diameter, 15(5) (2007). 69–72.

Google Scholar

[31] A.L. Andrady, Science and technology of polymer nanofibers John Wiley & Son Inc. Pub. (2007).

Google Scholar

[32] V. Pillay, C. Dott, Y.E. Choonara, C. Tyagi, L. Tomar, P. Kumar, L. C du Toit and V.M. K Ndesendo, A review of the effect of processing variables on the fabrication of electrospun nanofibers for drug delivery applications, Journal of Nanomaterials, 2013 (2013).

DOI: 10.1155/2013/789289

Google Scholar

[33] T.J. Sill and H.A. Von Recum, Electrospinning: applications in drug delivery and tissue engineering, Biomaterials. 29(13) (2008). 1989–(2006).

DOI: 10.1016/j.biomaterials.2008.01.011

Google Scholar