Removal of Cu, Fe, and Zn from Peat Water by Using Activated Carbon Derived from Oil Palm Leaves

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Heavy metal such as Cu, Fe, and Zn are the most serious contributers to environmental problems. The removal of heavy metal from the environment is the research interest nowdays. The adsorption of Cu, Fe and Zn from wastewater was investigated with various activated carbons as adsorbents. The activated carbons were produced from oil palm leaves by using multi-activation methods. The H3PO4, NaOH, ZnCl2 and KOH were chosen as chemical activating agents. Batch adsorption experiment was used to test the ability of activated carbon to remove Cu, Fe, and Zn from wastewater. The surface characteristics of activated carbon were evaluated using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FTIR), and nitrogen adsorption-desorption isotherms. The Activated carbons were able to purify wastewater with a maximum turbidity level of 2.83 NTU. The AC-H3PO4 activated carbon showed the highest absorbability of Cu metal as 91.540%, while the highest absorbabilities of Zn and Fe metals were indicated by AC-KOH activated carbon of 22.853% and 82.244% absorption respectively. Therefore, these results enable the oil palm leaves to become a high potential for activated carbon as removal the heavy metals.

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April 2021

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[1] W. S. Ritung, H. Subagjo, Peta sebaran lahan gambut, luas dan kandungan karbon di kalimantan/map of peatland distribution area and carbon content in kalimantan, 2000-2002. Wetlands International - Indonesia Programme & Wildlife Habitat Canada, Indonesia, 2004, p.234.

Google Scholar

[2] Y. Uraki, Y. Tamai, M. Ogawa, S. Gaman, S. Tokura, Preparation of activated carbon from peat, Bioresource 4 (2014) 205-213.

Google Scholar

[3] M. Karnib, A. Kabbani, H. Holail, Z. Olama, Heavy metals removal using activated carbon, silica, and silica activated carbon composite, Energy Procedia 50 (2014) 113-120.

DOI: 10.1016/j.egypro.2014.06.014

Google Scholar

[4] P. Brown, S. Gill, S. Allen, Metal removal from wastewater using peat, Water Research 34 (2000) 3907–3916.

DOI: 10.1016/s0043-1354(00)00152-4

Google Scholar

[5] G. Fadillah, E. N. K. Putri, S. Febrianastuti, E. V. Maylinda, C. Purnawan, Adsorption of Fe ions from aqueous solution using α-keratin-coated alginate biosorbent, Inter. J. Env. Sci. Dev. 9 (2017) 82-85.

DOI: 10.18178/ijesd.2018.9.3.1077

Google Scholar

[6] F. Cao, C. Lian, J. Yu, H. Yang, S. Lin, Study on the adsorption performance and competitive mechanism for heavy metal contaminants removal using novel multi-pore activated carbons derived from recyclable long-root Eichhornia crassipes, Bioresource Technol. 276 (2019) 211-218.

DOI: 10.1016/j.biortech.2019.01.007

Google Scholar

[7] A.M. Abioye, F.N Ani, Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: A review, Renew. Sustain. Ener. Rev. 52 (2015) 1282-1293.

DOI: 10.1016/j.rser.2015.07.129

Google Scholar

[8] Z.S. Iro, C. Subramani, S.S. Dash, A brief review on electrode materials for supercapacitor, Int. J. Electrochem. Sci. 11 (2016) 10628–10643.

DOI: 10.20964/2016.12.50

Google Scholar

[9] A. Ionnidou, Zabaniotu, Agricultural residues of precursors for activated carbon production-a review, Renew. Sustain. Ener. Rev. 11 (2007) 1705-1966.

Google Scholar

[10] Y.Z. Zhang, Z.J. Xing, Z.K. Duan, M. Li, Y. Wang, Effect of steam activation on the pore structure and surface chemistry of activated carbon derived bamboo waste, App. Surf. sci. 315 (2014) 279-286.

DOI: 10.1016/j.apsusc.2014.07.126

Google Scholar

[11] E. Taer, R. Taslim, W.S. Mustika, B. Kurniasih, Agustino, A. Afrianda, Apriwandi, Production of an activated carbon from a banana stem and its application as electrode materials for supercapacitors, Int. J. Electrochem. Sci. 13 (2018) 8428-8439.

DOI: 10.20964/2018.09.55

Google Scholar

[12] S. Kumagai, M. Sato, D. Tashima, Electrical double-layer capacitance of micro- and mesoporous activated carbon prepared from rice husk and beet sugar, Electrochim. Acta 114 (2013) 617–626.

DOI: 10.1016/j.electacta.2013.10.060

Google Scholar

[13] R. Farma, Deraman, Awitdrus, I.A. Talib, E. Taer, N.H. Basri, J.G. Manjunatha, M.M. Ishak, B.N.M. Dollah, S.A. Hashmi, Preparation of Highly Porous Binderless Astivated Carbon Electrodes from Fibers of Oil Palm Emty Fruit Bunches for Application in Supercapacitor, Bioresource technol. 132 (2013) 254-261.

DOI: 10.1016/j.biortech.2013.01.044

Google Scholar

[14] J.F. González, S. Román, J.M. Encinar, G. Martínez, Pyrolysis of various biomass residues and char utilization for the production of activated carbons, J. Anal. Appl. Pyrolysis 85 (2009) 134-141.

DOI: 10.1016/j.jaap.2008.11.035

Google Scholar

[15] E. Sari, Pasymi, U. Khatab, E.D. Rahman, Performance Evaluation of Rotary Carbonization Pyrolysis as Durian Shell Biobriquettes Raw Materials, Int. J. Eng. Tech. 4 (2018) 108-112.

Google Scholar

[16] F. Li, W. Chi, Z. Shen, Y. Wu, Y. Liu, H. Liu, Activation of mesocarbon microbeads with different textures and their application for supercapacitor, Fuel Process Technol. 91 (2010) 17-24.

Google Scholar

[17] D.B. Cullity Elements of X-Ray Diffraction, Ed. 3. Amazon: Prentice Hall (2001) p.253.

Google Scholar

[18] P.J.M. Carrott, J.M.V. Nabais, M.M.L.R. Carrott, J.A. Pajares, Preparation of activated carbon fibres from acrylic textiles fibres, Carbon 39 (2001) 1543-1555.

DOI: 10.1016/s0008-6223(00)00271-2

Google Scholar

[19] D. Qu, Studies of the activated carbons used in double-layer supercapacitors, J. Power Sources, 109 (2002) 403-441.

DOI: 10.1016/s0378-7753(02)00108-8

Google Scholar

[20] A. Allwar, Characteristics of pore structure and surface chemistry of activated carbons by physisorption, FTIR and Boehm methods, IOSR J. App. Chem. 2 (2012) 9-15.

DOI: 10.9790/5736-0210915

Google Scholar

[21] W.F. Smith, J. Hashemi, Foundations of materials science and engineering fifth edition in SI units. Singapore: The McGraw-Hill Companies, 2011, p.29.

Google Scholar

[22] M. Smisek, S. Cerny, Active carbon, manufacture, propertis, and aplications. Amsterdam, Elsevier Publishing Company, 1997, p.109.

Google Scholar

[23] W.S.K. Sing, H.D. Everett, W.A.R. Haul, L. Moscou, A.R. Pierotti, J. Rouquerol, T. Siemieniewska, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity, Pure and Applied Chemistry 57 (1985) 603-619.

DOI: 10.1515/iupac.57.0013

Google Scholar

[24] W.R. Li, D.H. Chen, Z. Li, Y.F. Shi, Y. Wan, G. Wang, Z.Y. Jiang, D.Y. Zhao, Nitrogen containing carbon spheres with very large uniform mesopores: superior electrode materials for EDLC inorganic electrolyte, Carbon, 45 (2007) 1757-1763.

DOI: 10.1016/j.carbon.2007.05.004

Google Scholar

[25] R. Farma, R. Fadilah, Awitdrus, N.K. Sari, E. Taer, Saktioto, M. Deraman, Corn cob based activated carbon preparation using microwave assisted potassium hydroxide activation for sea water purification, J. Phys. Conf. Ser. 1120 (2018) 012017-012021.

DOI: 10.1088/1742-6596/1120/1/012017

Google Scholar

[26] Z.M. Yunus, A. Al-Gheethi, N. Othman, R. Hamdan, N.N. Ruslana, Removal of heavy metals from mining effluents in tile and electroplating industries using honeydew peel activated carbon: A microstructure and techno-economic analysis, J. Cleaner Production 251 (2020) 119738-46.

DOI: 10.1016/j.jclepro.2019.119738

Google Scholar

[27] M.A.A. Zaini, L.L. Zhi, T.S. Hui, Y. Amano, M. Machida, Effects of physical activation on pore textures and heavy metals removal of fiber-based activated carbons, Materials Today: Proceedings (2020) 1-6.

DOI: 10.1016/j.matpr.2020.03.815

Google Scholar