Sinergy of Biodiesel and its Natural Antioxidant from Rice Bran Feedstock

Article Preview

Abstract:

Biodiesel tends to oxidation during the time of storage due to chemical structure, makes deterioration of fuel quality. Hence, the presence in feed stock required to gain standard quality for biodiesel commercialization. Natural antioxidant, mainly oryzanol found in rice bran feed stock, have been worked in biodiesel oxidation synergistic without any additional of synthetic antioxidant. In this work, the potential natural antioxidant has been evaluated by the oxidation stability. The biodiesel exhibited oxidation stability gained the induction period at 3 h by Rancimat method. It was found that the concentration of oryzanol above 300 ppm keep the biodiesel from oxidation. Even though very small amount 3 ppm oryzanol was obtained but contribute as cost implication due to antioxidants are costly chemicals. Otherwise adding synthetic antioxidant making high cost on biodiesel storage and utilization.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

55-63

Citation:

Online since:

January 2024

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A. E. Atabani, A. S. Silitonga, I. A. Badruddin, T. M. I. Mahlia, H. H. Masjuki, and S. Mekhilef, "A comprehensive review on biodiesel as an alternative energy resource and its characteristics," Renew. Sustain. Energy Rev., vol. 16, no. 4, p.2070–2093, 2012.

DOI: 10.1016/j.rser.2012.01.003

Google Scholar

[2] S. Zullaikah, C. C. Lai, S. R. Vali, and Y. H. Ju, "A two-step acid-catalyzed process for the production of biodiesel from rice bran oil," Bioresour. Technol., vol. 96, no. 17, p.1889–1896, 2005.

DOI: 10.1016/j.biortech.2005.01.028

Google Scholar

[3] Z. Yaakob, B. N. Narayanan, S. Padikkaparambil, S. Unni K., and M. Akbar P., "A review on the oxidation stability of biodiesel," Renew. Sustain. Energy Rev., vol. 35, p.136–153, 2014.

DOI: 10.1016/j.rser.2014.03.055

Google Scholar

[4] R. O. Dunn, "Oxidative stability of soybean oil fatty acid methyl esters by oil stability index (OSI)," JAOCS, J. Am. Oil Chem. Soc., vol. 82, no. 5, p.381–387, 2005.

DOI: 10.1007/s11746-005-1081-6

Google Scholar

[5] G. Knothe, "Some aspects of biodiesel oxidative stability," Fuel Process. Technol., vol. 88, no. 7, p.669–677, 2007.

DOI: 10.1016/j.fuproc.2007.01.005

Google Scholar

[6] S. Jain and M. P. Sharma, "Stability of biodiesel and its blends: A review," Renew. Sustain. Energy Rev., vol. 14, no. 2, p.667–678, 2010.

DOI: 10.1016/j.rser.2009.10.011

Google Scholar

[7] G. P. J. Seetharamaiah, "Oryzanol content of Indian rice bran oil and its extraction from soap stock," Food Sci. Technol., vol. 23, p.270–274, 1986.

Google Scholar

[8] M. Saska and C. J. Rossiter, "Recovery of γ-oryzanol from rice bran oil with silica-based continuous chromatography," JAOCS, J. Am. Oil Chem. Soc., vol. 75, no. 10, p.1421–1427, 1998.

DOI: 10.1007/s11746-998-0193-6

Google Scholar

[9] A. G. Gopala Krishna, S. Khatoon, P. M. Shiela, C. V. Sarmandal, T. N. Indira, and A. Mishra, "Effect of refining of crude rice bran oil on the retention of oryzanol in the refined oil," JAOCS, J. Am. Oil Chem. Soc., vol. 78, no. 2, p.127–131, 2001.

DOI: 10.1007/s11746-001-0232-0

Google Scholar

[10] M. Ghosh, "Review on recent trends in rice bran oil processing," JAOCS, J. Am. Oil Chem. Soc., vol. 84, no. 4, p.315–324, 2007.

DOI: 10.1007/s11746-007-1047-3

Google Scholar

[11] N. S. Kasim, H. Chen, and Y. H. Ju, "Recovery of γ-oryzanol from biodiesel residue," J. Chinese Inst. Chem. Eng., vol. 38, no. 3–4, p.229–234, 2007.

DOI: 10.1016/j.jcice.2007.02.002

Google Scholar

[12] M. García, L. Botella, N. Gil-Lalaguna, J. Arauzo, A. Gonzalo, and J. L. Sánchez, "Antioxidants for biodiesel: Additives prepared from extracted fractions of bio-oil," Fuel Process. Technol., vol. 156, p.407–414, 2017.

DOI: 10.1016/j.fuproc.2016.10.001

Google Scholar

[13] A. Sarin, N. P. Singh, R. Sarin, and R. K. Malhotra, "Natural and synthetic antioxidants: Influence on the oxidative stability of biodiesel synthesized from non-edible oil," Energy, vol. 35, no. 12, p.4645–4648, 2010.

DOI: 10.1016/j.energy.2010.09.044

Google Scholar

[14] R. Liu et al., "Antioxidant interaction of α-tocopherol, γ-oryzanol and phytosterol in rice bran oil," Food Chem., vol. 343, p.128431, 2021.

DOI: 10.1016/j.foodchem.2020.128431

Google Scholar

[15] T. C. P. M. Ramos et al., "Eugenol and TBHQ antioxidant actions in commercial biodiesel obtained by soybean oil and animal fat," Fuel, vol. 286, no. P1, p.119374, 2021.

DOI: 10.1016/j.fuel.2020.119374

Google Scholar

[16] C. V. Jemima Romola, M. Meganaharshini, S. P. Rigby, I. Ganesh Moorthy, R. Shyam Kumar, and S. Karthikumar, "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renew. Sustain. Energy Rev., vol. 145, no. March, p.111109, 2021.

DOI: 10.1016/j.rser.2021.111109

Google Scholar

[17] I. H. Rukunudin, P. J. White, C. J. Bern, and T. B. Bailey, "A modified method for determining free fatty acids from small soybean oil sample sizes," JAOCS, J. Am. Oil Chem. Soc., vol. 75, no. 5, p.563–568, 1998.

DOI: 10.1007/s11746-998-0066-z

Google Scholar

[18] Metrohm, "Application Bulletin 204/2 e - Oxidation stability of oils and fats – Rancimat method," Appl. Bull. 204/2 e, p.2–5, 2013, [Online]. Available: http://partners.metrohm.com/GetDocument?action=get_dms_document&docid=1184905

Google Scholar

[19] T. Issariyakul and A. K. Dalai, "Biodiesel from vegetable oils," Renew. Sustain. Energy Rev., vol. 31, p.446–471, 2014.

DOI: 10.1016/j.rser.2013.11.001

Google Scholar

[20] F. M. Ramezanzadeh, R. M. Rao, M. Windhauser, W. Prinyawiwatkul, and W. E. Marshall, "Prevention of oxidative rancidity in rice bran during storage," J. Agric. Food Chem., vol. 47, no. 8, p.2997–3000, 1999.

DOI: 10.1021/jf981168v

Google Scholar

[21] O. Benito-Román, S. Varona, M. T. Sanz, and S. Beltrán, "Valorization of rice bran: Modified supercritical CO2 extraction of bioactive compounds," J. Ind. Eng. Chem., vol. 80, p.273–282, 2019.

DOI: 10.1016/j.jiec.2019.08.005

Google Scholar

[22] B. R. Yi, J. H. Lee, and M. J. Kim, "Increasing oxidative stability in corn oils through extraction of γ-oryzanol from heat treated rice bran," J. Cereal Sci., vol. 91, p.102880, 2020.

DOI: 10.1016/j.jcs.2019.102880

Google Scholar

[23] E. T. Denisov and I. V. Khudyakov, Mechanisms of Action and Reactivities of the Free Radicals of Inhibitors, vol. 87, no. 6. 1987.

DOI: 10.1021/cr00082a003

Google Scholar

[24] G. W. Burton et al., "Autoxidation of Biological Molecules. 4. Maximizing the Antioxidant Activity of Phenols," J. Am. Chem. Soc., vol. 107, no. 24, p.7053–7065, 1985.

DOI: 10.1021/ja00310a049

Google Scholar

[25] S. Kerkering, W. Koch, and J. T. Andersson, "Influence of phenols on the oxidation stability of home heating oils/FAME blends," Energy and Fuels, vol. 29, no. 2, p.793–799, 2015.

DOI: 10.1021/ef502260d

Google Scholar

[26] P. J. O. and P. L. A. P. Nakul Singh, "Mechanistic aspects of hydrogen abstraction for phenolic antioxidants. Electronic structure and topological electron density analysis," Phys . Chem. Chem. Phys . , 2 0 0 5 , 7 , 6 1 4 – 6 1 9, 2005.

DOI: 10.1039/b415075a

Google Scholar

[27] M. R. Toorani, R. Farhoosh, M. Golmakani, and A. Sharif, "Antioxidant activity and mechanism of action of sesamol in triacylglycerols and fatty acid methyl esters of sesame, olive, and canola oils," Lwt, vol. 103, no. November 2018, p.271–278, 2019.

DOI: 10.1016/j.lwt.2019.01.012

Google Scholar

[28] G. Karunanithi, A. Mozhi, and S. Varadappan, "Exploring the effectiveness of novel Coffea Arabica leaf pigment as a natural antioxidant additive for date seed biodiesel," Fuel, vol. 324, no. PA, p.124561, 2022.

DOI: 10.1016/j.fuel.2022.124561

Google Scholar

[29] Y. C. Liang, C. Y. May, C. S. Foon, M. A. Ngan, C. C. Hock, and Y. Basiron, "The effect of natural and synthetic antioxidants on the oxidative stability of palm diesel," Fuel, vol. 85, no. 5–6, p.867–870, 2006.

DOI: 10.1016/j.fuel.2005.09.003

Google Scholar

[30] "Renewable Energy Market Update - May 2022," International Energy Agency, 2022. https://www.iea.org/data-and-statistics/charts/biodiesel-and-diesel-prices-2019-to-april-(2022)

Google Scholar

[31] M.-T. G. Mohamad Reza Toorani, "Effect of triacylglycerol structure on the antioxidant activity of γ-oryzanol," vol. LWT, 2022.

Google Scholar

[32] M. Hossain, S. S. Israt, N. Muntaha, and M. S. Jamal, "Effect of antioxidants and blending with diesel on partially hydrogenated fish oil biodiesel to upgrade the oxidative stability," Bioresour. Technol. Reports, vol. 17, no. October 2021, p.100938, 2022.

DOI: 10.1016/j.biteb.2021.100938

Google Scholar