Preparation and Characterization of Functionalized Graphene/Linear Low Density Polyethylene Nanocomposites

Article Preview

Abstract:

The present work deals with the functionalization of graphene sheet and preparation of functionalized graphene/linier low density polyethylene (LLDPE) nanocomposites by solution-mix techniques. Dodecyl amine (DA) has been used for the surface modification of graphene oxide (GO) and hydrazine as reducing agent. Fourier transform infrared (FTIR) spectra exhibits the appearance of new peaks in the functionalized graphene (DA-G), which suggests the functionalization of graphene by DA. X-ray diffraction (XRD) analysis infers the formation of fully exfoliated DA-G/LLDPE nanocomposites. The tensile strength (TS) and elongation at break (EB) of the composites are higher in comparison to neat LLDPE. The nanocomposites with only 0.5 wt.% of DA-G content results in TS and EB to be 17% and 10% higher compared to neat LLDPE. TGA shows that the thermal stability of the DA-G/LLDPE nanocomposites is higher compared to pure matrix polymer.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 123-125)

Pages:

173-176

Citation:

Online since:

August 2010

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2010 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] A.K. Geimm, K.S. Novoselov: Nat. Mater. Vol. 6 (2007), p.183.

Google Scholar

[2] P.L. Andres, R. Ramírez, J.A. Vergés: Phy. Rev. B vol. 77 (2008), p.0454031.

Google Scholar

[3] M.J. Allen, V.C. Tung, R.B. Kaner: Chem. Rev. vol. 110 (2010), p.132.

Google Scholar

[4] N.A. Kotov, I, Dekany, J.H. Fendler: Adv. Mater. Vol. 8 (1996), p.637.

Google Scholar

[5] K.S. Kim, Y. Zhao, H. Jang, S.Y. Lee, J.M. Kim, K.S. Kim, et al: Nature vol. 457 (2009), p.706.

Google Scholar

[6] S. Stankovich, D.A. Dikin, G.H.B. Dommett, K.M. Kohlhaas, E.J. Zimney, E.A. Stach, et al: Nature vol. 442 (2006), p.282.

DOI: 10.1038/nature04969

Google Scholar

[7] H. Kim, C.W. Macosko: Polymer vol. 50 (2009), p.3797.

Google Scholar

[8] H. Hu, X. Wang, J. Wanga, L. Wana, F. Liu, H. Zheng, et al: Chem. Phys. Lett. Vol. 484 (2010), p.247.

Google Scholar

[9] S. Niyogi, E. Bekyarova, M.E. Itkis, J.L. McWilliams, M.A. Hamon, R.C. Haddon: J. Am. Chem. Soc. Vol. 128 (2006), p.7720.

DOI: 10.1021/ja060680r

Google Scholar

[10] Y. Xu, H. Bai, G. Lu, C. Li, G. Shi: J. Am. Chem. Soc. Vol. 130 (2008), p.5856.

Google Scholar

[11] N. Liu, F. Luo, H.X. Wu, Y.H. Liu, C. Zhang, J. Chen: Adv. Funct. Mater. Vol. 18(2008), p.1518.

Google Scholar

[12] A.B. Bourlinos, D. Gournis, D. Petridis, T. Szabo, A. Szeri, I. Dekany: Chem. Mater. Vol. 19 (2003), p.6050.

Google Scholar

[13] W.S. Hummers, R.E. Offeman: J. Am. Chem. Soc. Vol. 80 (1958), p.1339.

Google Scholar

[14] J.I. Paredes, S. Villar-Rodil, A. Martinez-Alonso, J.M.D. Tascon: Langmuir vol. 24 (2008), p.10560.

Google Scholar