Dimethyl Ether Catalytic Combustion over Manganese Oxides with Different Structures

Article Preview

Abstract:

α-MnO2, β-MnO2 and Mn2O3 were synthesized from birnessite followed by acid treatment and subsequently calcined under different conditions. These catalysts were used for catalytic combustion of dimethyl ether (DME) and characterized by XRD, BET and H2-TPR techniques. The results showed that the catalytic activity of α-MnO2, β-MnO2 and Mn2O3 are higher than that of birnessite. Larger specific surface area as well as the better reducibility of Mn species in the manganese oxides might be the main contribution for the DME combustion activity.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 146-147)

Pages:

1482-1485

Citation:

Online since:

October 2010

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] D. Jin, B. Zhu, Z. Hou, J. Fei, H. Lou, X. Zheng. Fuel. Vol. 86. (2007), p.2707.

Google Scholar

[2] J. X. Hou, X. Q. Qiao, Z. Wang, W. Liu. J. Energy. Inst. Vol. 83. (2010), p.63.

Google Scholar

[3] F. Solymosi, J. C. Enyi, L. O. Ari. J Catal. Vol. 171. (1997), p.476.

Google Scholar

[4] A. Ishikawa, E. Iglesia. Chem Commun. Vol. (2007), p.2992.

Google Scholar

[5] A. Ishikawa, E. Iglesia. J Catal. Vol. 252. (2007), p.49.

Google Scholar

[6] E. Wortham, B. Bonnet, D. J. Jones, J. Roziere. J Mater Chem. Vol. 14. (2004), p.121.

Google Scholar

[7] F. Li, J. F. Wu, Q. H. Qin, Z. Li, X. T. Huang. J Alloy Compd. Vol. 492. (2010), p.339.

Google Scholar

[8] I. Atribak, A. Bueno-Lopez, A. Garcia-Garcia, P. Navarro, D. Frias, M. Montes. Appl. Catal. B. Vol. 93. (2010), p.267.

Google Scholar

[9] W. Xiao, D. L. Wang, X. W. Lou. J. Phys. Chem. Vol. 114. (2010), p.1694.

Google Scholar

[10] G. Q. Diao, L. Yu, M. Sun, Q. Yu, F. Q. Fan. Chin J Catal. Vol. 30. (2009), p.1114. (In Chinese).

Google Scholar

[11] L. Yu, M. Sun, J. Yu, Q. Yu, Z. Hao, C. Li. Chin J Catal. Vol. 29. (2008), p.1127.

Google Scholar

[12] G. S. Cao, L. Su, X. J. Zhang, H. Li. Mater Res Bull. Vol. 45. (2010), p.425.

Google Scholar

[13] X. Tang, Z. Su, Y. Han, Z. H. Liu. Colloid Surface A. Vol. 317. (2008), p.443.

Google Scholar

[14] Y. Yin, W. Xu, Y. Shen, S. L. Suib, C. L. O'Young. Chem Mater. Vol. 6. (1994), p.1803.

Google Scholar

[15] J. Luo, Q. Zhang, J. Garcia-Martinez, S. L. Suib. J Am Chem Soc. Vol. 130. (2008), p.3198.

Google Scholar