A Laser-Imageable Thermo-Sensitive Film Based on Tertiary Amine Oxide-Containing Resin

Article Preview

Abstract:

A modified phenolic resin containing tertiary amine oxide was prepared via a two-step method. Epoxy phenolic resin, F-48, was reacted with dimethylamine to give the phenolic resin containing the tertiary amine group, which was then oxidized with hydrogen peroxide to obtain the target product. The tertiary amine oxide-containing resin could easily dissolve in water. However, it became water insoluble after heat treatment at a high temperature such as 160 °C. Thermal properties of the tertiary amine oxide resin were studied with DSC and TGA. A thermo-sensitive film comprising the prepared resin and an IR-dye was prepared and laser-induced thermal imaging was also conducted. This material might be used to develop new chemistry-free printing plates.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 156-157)

Pages:

1410-1414

Citation:

Online since:

October 2010

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] R.M. Adams, F.J. Romano and F. Romano: Computer-to-Plate: Automating the Printing Industry (GATF Press, U.S. A 1998).

Google Scholar

[2] S. Christopher, B. Harald and S. Bernd, WO 2009109579. (2009).

Google Scholar

[3] B. Harald, D. Udo, S. Bernd, S. Christopher, S. -H. Celin and H. Gerhard, WO 2009073098. (2009).

Google Scholar

[4] Bolli , Angelo, Tettamanti, U.S. Patent 7, 144, 681. (2006).

Google Scholar

[5] Y. Sakaguchi, K. Kawahara, T. Yamada, Y. Okazaki and S. Imahashi: J. Appl. Polym. Sci. Vol. 92 (2004), p.2903.

Google Scholar

[6] A. Igarashi, K. Arimitsu, K. Aoki and K. Ichimura: J. Photopolym. Sci. Technol. Vol. 18 (2005), p.419.

Google Scholar

[7] G.G. Umarji, S.A. Ketkar, G.J. Phatak, V.D. Giramkar, U.P. Mulik and D.P. Amalnerkar: Microelectronics and Reliability Vol. 45 (2005) , p. (1903).

DOI: 10.1016/j.microrel.2005.03.007

Google Scholar

[8] J.L. Pu, H.B. Guo, J. Wu and Z.X. Li: Eur. Polym. J. Vol. 43 (2007) , p. (2057).

Google Scholar

[9] Z.X. Li, Y.G. Feng, L.H. Li and J.L. Pu: Eur. Polym. J. Vol. 44 (2008) , p.1899.

Google Scholar

[10] Y.X. Gao, Y.Z. Bao , Z.M. Huang and Z.X. Weng: Photograph. Sci. Photochem. Vol. 22 (2004) , p.33 (in Chinese).

Google Scholar

[11] D.H. Wang , L. Jiang : Theory and applications of ultraviolet curing materials (Science Press, P.R.C., 2001).

Google Scholar

[12] J.T. Duan, M.C. Xu, H.T. Li, Z.Q. Shi and B.L. He: Ion Exch. Adsorpt. Vol. 20 (2004) , p.40 (in Chinese).

Google Scholar

[13] (a) J.B. Hendersona, M.R. Tanta, G.R. Moorea and J.A. Wiebeltb: Thermochimica Acta, Vol. 44(1981) , p.253 , (b) Y. Zhang, J.G. Wang, Y.J. Liu and M.W. Li: Aerospace Mate. Tech. Vol. 5 (2003) , p.35.

Google Scholar