Adsorption Properties of Self-Assembly Synthesized Microporous Silica Material from Acidic Aqueous Media

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Abstract:

Microporous silica material AMPS has been synthesized via TEA+ cations assisted self-assembly of silica species in acidic aqueous solution. Nitrogen adsorption analysis revealed 0.65 nm uniform micropores in AMPS, companied with a Langmuir surface area of 745 m2/g and a pore volume of 0.22 cm3/g. The microporous AMPS exhibited an excellent adsorptive performance for volatile organic compounds (VOC) such as cyclohexane and acetone, compared with conventional zeolites such as Y, ZSM-5 and A. The adsorption was rapidly saturated at lower relative pressure with higher capacities than that of conventional zeolites. These features implied promising potentials in the separation and removal of VOCs in the atmosphere by using APS-3.

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Advanced Materials Research (Volumes 179-180)

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519-522

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January 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] Z. Y. Du and X. B. Sun: Adv. Mater. Res., Vol. 113-114 (2010), p.146.

Google Scholar

[2] J. Pires, A. Carvalho, P. Veloso, and M. B. Carvalho: J. Mater. Chem., Vol. 12 (2002), p.3100.

Google Scholar

[3] S. -W. Baek, J. -R. Kim, S. -K. Ihm: Catal. Today, Vol. 93-95 (2004), p.575.

Google Scholar

[4] M. E. Davis: Nature, Vol. 417 (2002), p.813.

Google Scholar

[5] B. M. Lok, T. R. Cannan and C. A. Messina: Zeolites, Vol. 3 (1983), p.282.

Google Scholar

[6] C. S. Cundy and P. A. Cox: Chem. Rev., Vol. 103 (2003), p.663.

Google Scholar

[7] C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli and J. S. Beck: Nature, Vol. 352 (1991), p.710.

Google Scholar

[8] D. Zhao, J. Feng, Q. Huo, N. Melosh, G. H. Fredrickson, B. F. Chmelka and G. D. Stucky: Science, Vol. 279 (1998), p.548.

Google Scholar

[9] A. Imhof and J. Pine: Nature, Vol. 389 (1997), p.948.

Google Scholar

[10] A. Djalma, B. Filho, C. Hisano, R. Bertholdo, M. G. Schiavetto, C. Santilli, S. J. L. Ribeiro and Y. Messaddeq: J. Colloid Interface Sci., Vol. 291 (2005), p.448.

DOI: 10.1016/j.jcis.2005.05.016

Google Scholar

[11] S. A. Bagshaw and A. R. Hayman: Chem. Commun., Vol. 6 (2000), p.533.

Google Scholar

[12] Y. Di, X. Meng, S. Li and F.S. Xiao: Langmuir, Vol. 22 (2006), p.3068.

Google Scholar

[13] J-L. Paillaud, B Harbuzaru, J. Patarin and N. Bats: Science, Vol. 304 (2004), p.990.

Google Scholar

[14] A. Corma, M. J. Díaz-Cabañas, F. Rey, S. Nicolopoulusa and K. Boulahya: Chem. Commun., Vol. 12 (2004), p.1356.

Google Scholar