Magnesium-Based Hydrogen-Storage Materials from Milling for Sulfocompound Hydrodesulfurization

Shi Xue Zhou; Ming Lin Zhang; Hai Li Niu; Tong Huan Zhang; Hai Peng Chen

doi:10.4028/www.scientific.net/AMR.194-196.421

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 194-196Magnesium-Based Hydrogen-Storage Materials from...

Magnesium-Based Hydrogen-Storage Materials from Milling for Sulfocompound Hydrodesulfurization

Abstract:

Magnesium-based hydrogen-storage materials were prepared by reactive ball-milling under hydrogen atmosphere. It was shown that crystallitic carbon from anthracite carbonization was an effective milling aid for magnesium. Dispersive nano-particles about 20 to 60 nm were prepared from magnesium with 35 wt.% of crystallitic carbon additive by milling for 3 h under 1 MPa of hy-drogen atmosphere. The magnesium hydrided into MgH2 and the crystallitic carbon was endowed with C=CH₂ functional group during milling. The hydrogen-storage materials were used for the hy-drodesulfurization of CS₂ and thiophene, and H₂S and MgS yielded after reaction. To add molybdenum into the hydrogen-storage materials was in favor of the hydrogenation of sulfo-compounds.

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Periodical:

Advanced Materials Research (Volumes 194-196)

Pages:

421-424

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.194-196.421

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Online since:

February 2011

Authors:

Shi Xue Zhou, Ming Lin Zhang, Hai Li Niu, Tong Huan Zhang, Hai Peng Chen

Keywords:

Crystallitic Carbon, Hydrodesulfurization, Hydrogen-Storage Material, Magnesium, Reactive Milling, Sulfocompound

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