In this paper, various kinds of high-temperature phase change thermal storage Al-Si-Cu-Mg-Zn alloys were prepared, and the thermal properties were studied through integrated thermal analysis. Then the corrosion kinetics of Cr20Ni80 alloy in Al-7% Si alloy and Al-Cu-Mg-Zn alloy at 700°C in thermal cycles were obtained. The microstructures, element concentration and phases in the interface were analyzed by means of metallographic microscope, EPMA and XRD. The results show that all materials phase transition temperatures are during 450°C ~650°C . The total thermal energies of the materials are higher than 900J/cm3. Quaternary alloys and quinary alloys show much more advantages when applying for solar thermal power generation systems. The latent heat depends strongly upon the composition and percentage of elements and the phase composition. Besides, experimental results show that the corrosion rate of Cr20Ni80 alloy in Al-7%Si alloy at 700°C is 0.167mm/h. Under thermal cycling conditions, the corrosion rate of Cr20Ni80 alloy in Al-Cu-Mg-Zn alloy is a little lower and the reaction interface layer does not significantly affect the rate of further corrosion. The corrosion of Al-Si-Cu-Mg-Zn phase change thermal storage materials depends on the content of aluminum element, and nickel-based alloys are not suitable for use as packaging materials.