Synthesis, Characterization and DNA-Binding Studies of Transition Metal Complexes with Imidazole Ligands

Jun Wang; Xiang Rong Liu; Yu Jin Sun; Kan She Li; Shun Sheng Zhao

doi:10.4028/www.scientific.net/AMR.233-235.175

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 233-235Synthesis, Characterization and DNA-Binding...

Synthesis, Characterization and DNA-Binding Studies of Transition Metal Complexes with Imidazole Ligands

Abstract:

A series of novel complexes of transition metal (Co, Fe and Mn) with imidaloze have been synthesized and characterized by Elemental Analysis, FT-IR and UV-Vis Absorption spectroscopy. Based on elemental and spectral data, the complexes were found to be of Co(C₃H₄N₂)₄(ClO₄)₂ (1), Fe(C₃H₄N₂)₃(ClO₄)₃ (2) and Mn(C₃H₄N₂)₄(Ac)₂ (3) (C₃H₄N₂= imidazole). The three complexes and the ligand (imidazole) display DNA binding ability, ascertained by UV-Vis titration.

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Advanced Materials Research (Volumes 233-235)

Pages:

175-179

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https://doi.org/10.4028/www.scientific.net/AMR.233-235.175

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Online since:

May 2011

Authors:

Jun Wang, Xiang Rong Liu, Yu Jin Sun, Kan She Li, Shun Sheng Zhao

Keywords:

Imidazole, Interaction with CT-DNA, Transition Metal

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References

[1] R.N. Patel, N. Singh, V.L.N. Gundla: Polyhedron, 25 (2006), 3315.

Google Scholar

[2] R.N. Patel, V.L.N. Gundla, D.K. Patel: Polyhedron, 27 (2008), 1057.

Google Scholar

[3] Majella Geraghty, Malachy McCann, Michael Devereux, Vickie McKee: Inorganica Chimica Acta., 293 (1999), 160.

Google Scholar

[4] Shuyan Niu, Shusheng Zhang, Long Wang, Xuemei Li: Journal of Electroanalytical Chemistry, 597 (2006), 111.

Google Scholar

[5] K.E. Erkkila, D.T. Odom, J.K. Barton: Chem. Rev., 99 (1999), 2777.

Google Scholar

[6] C. Metcalfe, J.A. Thomas: Chem. Soc. Rev., 32 (2003), 215.

Google Scholar

[7] A.M. Pyle, J.P. Rehmann, R. Meshoyrer, C.V. Kumar, N.J. Turro, J.K. Barton: J. Am. Chem. Soc., 111 (1989), 3051.

DOI: 10.1021/ja00190a046

Google Scholar

[8] H. Catherine, P. Marguerite, R.G. Michael, M. Bernard: J. Biol. Inorg. Chem., 6 (2001), 14.

Google Scholar

[9] V.S. Li, D. Choi, Z. Wang, L.S. Jimenez, M.S. Tang, H. Kohn: J.Am.Chem.Soc., 118 (1996), 2326.

Google Scholar

[10] G. Zuber, J.C. Quada Jr., S.M. Hecht: J. Am. Chem. Soc., 120 (1998), 9368.

Google Scholar

[11] M. Arif, Nazir, M.S. Iqbal, S. Anjum: Inorganica Chimica Acta., 362 (2009), 1626.

Google Scholar

[12] Zhihong Xu, Fengjuan Chen, Pinxian Xi, Xiaohui Liu, Zhengzhi Zeng: Journal of Photochem- istry and Photobiology A: Chemistry, 196 (2008), 80.

Google Scholar

[13] Lei Jia, Peng Jiang, Jun Xu, Zhongyan Hao, Ximing Xu, Longhai Chen, Jincai Wu, Ning Tang, Qin Wang, Jagadese J. Vitta: Inorganica Chimica Acta., 363 (2010), 857.

Google Scholar

[14] Xiaoyu Liu: Journal of Beijing Union University (Natural Sciences), 23 (2009), 20 (In Chinese).

Google Scholar

[15] A. Tarushi, G. Psomas, C.P. Raptopoulou, V. Psycharis, D.P. Kessissoglou: Polyhedron, 28 (2009), 3275.

DOI: 10.1016/j.poly.2009.04.003

Google Scholar