For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
Study on Properties of Polyacrylamide Emulsion and Pilot Test of its Crosslinking System Used for EOR
p.2056
Application of Shotcrete Linings under Sulfate Attack Environments
p.2061
Thermodynamic Equilibrium Diagram of Oxygen-Chlorine-Titanium System
p.2068
Experimental Study of Light-Repair on Composite Material Deflection
p.2072
Dynamic Mechanical and Thermal Behavior of UV-Curable Coating of Glycidyl Methacrylate /Polyurethane-Acrylate Modified with MAP-POSS
p.2077
Synthesis of Monodisersed PSt-g-PNIPAAm Nanospheres by UV Initiated Dispersion Polymerization
p.2081
Study on the Property Right of Emission Trading in China
p.2087
Enhancement of Crystalization and Photocatalysis of Bi2MoO6 Nanoplates by SDS Assisted Hydrothermal Method
p.2091
Research Survey on Synthesis Methods of Silicon Nanowires
p.2098

Dynamic Mechanical and Thermal Behavior of UV-Curable Coating of Glycidyl Methacrylate /Polyurethane-Acrylate Modified with MAP-POSS

Article Preview

Abstract:

UV-curable bi-component coating of glycidyl methacrylate (GMA)/polyurethane –acrylate (PUA) modified with the methylacryloylpropyl polyhedral oligomeric silsesquioxanes (MAP-POSS) were prepared. The dynamic mechanical properties and thermal behavior of nano-hybrid coating (GMA/PUA/MAP-POSS) were characterized with dynamic mechanical analysis (DMA), thermogravimetric analysis (TGA) and the Fourier transform infrared spectrometer (FTIR). The results indicate the three components have very good compatibility and can co-cure in UV-radialization by a free radical polymerization. The addition of MAP-POSS enhanced the thermal properties, the mechanical loss peak temperature Tp is 85.5°C when the amount of MAP-POSS is 10wt%, which is increased by 12.6 °C than the pure system. When the content of MAP-POSS is 20wt%, thermal decomposition temperature in the initial stages was increased by 7 °C than that of the pure GMA/ PUA.

You might also be interested in these eBooks
Fundamental of Chemical Engineering View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 233-235)

Pages:

2077-2080

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.233-235.2077

Citation:

Cite this paper

Online since:

May 2011

Authors:

Jun Gang Gao, Ying Ying Ma, Hao Jie Lin, Li Huo

Keywords:

Glycidyl Methacrylate, Polyurethane-Acrylate, Silsesquioxane (SSO), UV-Curable Coating

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] H. C. Miller: Modern Paint & Coatings Vol. 83(12) (1993), pp.40-43

Google Scholar

[2] J. W. Hong, H. K. Kim, J. A. Yu and Y. B. Kim: J Appl Polym Sci Vol. 84 (2002), pp.132-137

Google Scholar

[3] I. E. dell'Erba and R. J. J. Williams: Eur Polym J Vol. 43(2007), pp.2759-2767

Google Scholar

[4] I. A. Zucchi, M. J. Galante and R. J. J. Williams: Eur Polym J Vol. 45 (2) (2009), pp.325-331

Google Scholar

[5] H. Saito, M. Isozaki: Japan Patent [31] 285387. (2002)

Google Scholar

[6] J. G. Gao, C. J. Jiang and X. J. Zhang: Inter J Polym Mater 56, 6576 (2007).

Google Scholar

[7] D. Shen, Application of Infrared Spectrum in Polymer, pp.88-100, Science Press, Beijing (1982).

Google Scholar

[8] M. J. He, H, D, Zhang, W. X. Chen and X. X. Dong: Polymer Physics, pp.240-246, Fu Dan Univ. Press, Shanghai, China (2007).

Google Scholar

[9] J. Macan, I. Brnardic, S. Orlic, H. Lvankoyic and M. Lvankoyic: Polym Degrad Stabil. Vol. 91 (2006), pp.122-127

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.