Synthesis of Epoxidized Rubber Seed Oil

Abstract:

The liquefaction of cellulose in the presence of phenol without or with sulfuric acid as catalyst was investigated. The liquefied products were characterized by GC/MS and FTIR. Results showed that reaction temperature and reaction time had obvious effects on liquefaction of cellulose. Sulfuric acid showed an excellent catalytic degradation. The chemical compositions of the liquefied products produced using sulfuric acid catalyst or not were almost identical, and the majority of the identified liquefied products were methylene bisphenol and its isomers. During the process of liquefaction, the degradation of cellulose and condensation polymerization occurred at the same time. The last liquefied products were greatly dependent on the reaction conditions.

• Periodical: Advanced Materials Research (Volumes 236-238)
• Pages: 247-252
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.236-238.247
• Online since: May 2011
• Authors: Yuan Bo Huang, Zhi Feng Zheng, Ji You Gu, Yun Wu Zheng, Qing Li Qin, Guan Dong Wang
• Keywords: Epoxidation, Peroxyacetic Acid, Plasticizer, Rubber Seed Oil

References

[1] V. V. Goud, A. V. Patwardhan and N. C. Pradhan: Bioresour. Technol., Vol.97 (2006), p.1365.

[2] S. Dinda S, A. V. Patwardhan and V. V. Goud: Bioresour. Technol., Vol.99 (2008), p.3737.

[3] C. G. Ma, R. H. Guo and K. H. Zhang: China Oils and Fats, Vol.34 (2009), p.57. (In Chinese)

[4] M. A. R. Meier, J. O. Metzger and U. S. Schubert: Chem. Soc. Rev., Vol.36 (2007), p.1788.

[5] N. N. Pillai and R. T. Wijewantha: Rubber Res. Inst. Ceylon Bull., Vol.2 (1967), p.8.

[6] Y. Chen, L. H. Zheng, K. Zhao, H. R. Gao and S. F. Pan: China Oils and Fats, Vol.35 (2009), p.57. (In Chinese)

[7] F. E. Okieimen, O. I. Bakare and C. O. Okieimen: Ind. Crops. Prod., Vol.15 (2002), p.139.

[8] H. P. Wu, S. Jiang, Y.Y. Xu and J. Z. Chen: Journal of Chemical Engineering of Chinese Universities, Vol.23 (2009), p.116. (In Chinese)

[9] H. L. D. Mamat; N. E. Mamat and W. M. J. Aili: Chemical Industry and Engineering Progress, Vol.25 (2006), p.581. (In Chinese)

[10] J. C. Chen and H. Huang: China Oils and Fats, Vol.34 (2009), p.48. (In Chinese)

[11] Y. Wu, J. F. Wei, M. Zhang and Y. Q. Miao: Chemical Industry, Vol.34 (2005), p.119. (In Chinese)

[12] X. Y. Sun, X. B. Zhao, W. Du and D. H. Liu: The Chinese Journal of Process Engineering, Vol.10 (2010), p.714. (In Chinese)

[13] Y. X. He, G. M. Li and X. Liu: Chinese Journal of Applied Chemistry, Vol.27(2010), p.27. (In Chinese)