Influence of frictional wear characteristics of the cast iron-cast iron friction pair were investigated in the Self-repairing Additive with different concentration by using MMU-5G end-face friction and wear testing machine. The capability of generating self-repair coatings on the cast iron tribo-surface was verified in the Self-repairing Additive. The surface images of friction pair and their chemical composition were detected by using SEM and EDS. The result indicates different concentration has a great influence on frictional wear characteristics of friction pair in the Self-repairing Additive. In the self-repairing Additive, the Self-repair coatings are not formed on the cast-iron worn surface; self-repairing Additive has remarkable effect on antifriction and wearing of cast iron.