Effect of V2O5 and ZnO Additives on the Sintering Temperature and Microwave Dielectric Properties of Ca[(Li1/3Nb2/3) 0.8Ti 0.2]O3-δ Ceramics

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Abstract:

Low-temperature sintered Ca[(Li1/3Nb2/3)0.8Ti0.2]O3-δ (CLNT) microwave dielectric ceramics with V2O5 and ZnO additives were prepared by the conventional solid state reaction method. The sintering behavior and microwave dielectric properties of CLNT ceramics were investigated. The main diffraction peaks of all the specimens sintered at the temperature under 1150C split due to the coexistence of the non-stoichiometric phase and stoichiometric phase, which all possess CaTiO3-type perovskite structures. ZnO and V2O5 combined additives lowered the sintering temperature of CLNT ceramics from 1150C to 1090C. and the Qf values were improved from 18,210 GHz to 20,740 GHz. The CLNT ceramics with 4 wt% ZnO addition sintered at 1090C showed good microwave dielectric properties with εr ~39.7, Qf ~20,740 GHz, τf ~8.6 ppm/C. The relationship between dielectric properties and the sintering behavior was also discussed.

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Advanced Materials Research (Volumes 239-242)

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77-80

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May 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] D. W. Kim, D. G. Lee, and K. S. Hong: Mater. Res. Bull. Vol. 36 (2001), p.585

Google Scholar

[2] J. W. Choi, C. Y. Kang, S. J. Yoon, et al.: J. Mater. Res. Vol. 14 (1999), p.3567

Google Scholar

[3] D. H. Kim, C. An, Y. S. Lee, et al.: J. Mater. Sci. Lett. Vol. 22 (2003), p.569

Google Scholar

[4] A. Y. Borisevich and P. K. Davies: J. Eur. Ceram. Soc. Vol. 21 (2001), p.1719

Google Scholar

[5] D. Zhou, H. Wang, X. Yao, et al.: App. Phy. Lett. Vol. 90 (2007), p.172910.

Google Scholar

[6] J. X. Tong, Q. L. Zhang, H. Yang,et al.: Mater. Lett. Vol. 59 (2005), p.3252

Google Scholar

[7] C. L. Huang, J. L. Hou, C. L. Pan, et al.: J. Alloy. Compd. Vol. 450 (2008), p.359

Google Scholar

[8] Q. Zeng, W. Li, J. L. Shi, et al.: J. Am. Ceram. Soc. Vol. 90 [7] (2007), p.2262

Google Scholar

[9] B. W. Hakki, P. D. Coleman, IRE Trans: Microwave Theory Tech., MTT 8 (1960), p.402

Google Scholar

[10] J. Krupka, K. D. Derzakowski, B. Riddle, et al.: Meas. Sci. Technol. 9 (1998), p.1751

Google Scholar

[11] J. X. Tong, Q. L. Zhang, H. Yang, et al.: J. Am. Ceram. Soc. Vol. 90[3] (2007), p.845

Google Scholar