Solid-Liquid Reaction Synthesis and Characterization of Bioinorganic Complexes of Nicotinic Acid with Antimony(III) and Bismuth(III) Ion

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Abstract:

Bioinorganic complexes of nicotinic acid with trivalent antimony and bismuth are synthesized by solid-liquid reaction at room temperature. The formula of the complexes is Sb(C5H4NCOOH)2Cl3•H2O and Bi(C5H4NCOOH)2Cl3•H2O respectively. The crystal structure of the complex of nicotinic acid and Sb(III) belongs to triclinic system and that of nicotinic acid and Bi(III) belongs to monoclinic system. Thermal analysis can indicate the complex formation between antimony or bismuth ion and nicotinic acid.

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Advanced Materials Research (Volumes 282-283)

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267-270

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July 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] V. Stavila, R.L. Davidovich, A. Gulea and K. H. Whitmire: Coord. Chem. Rev. Vol. 250 (2006), p.2782.

Google Scholar

[2] M. Mehring: Coord. Chem. Rev. Vol. 251 (2007), p.974.

Google Scholar

[3] G.Q. Zhong, S.R. Luan, P. Wang, Y.C. Guo, Y.R. Chen and Y.Q. Jia: J. Therm. Anal. Calor. Vol. 86 (2006) , p.775.

Google Scholar

[4] G.Q. Zhong, J. Shen, Q.Y. Jiang, Y.Q. Jia, M.J. Chen and Z.P. Zhang: J. Therm. Anal. Calorim. Vol. 92 (2008), p.607.

Google Scholar

[5] Q.Y. Jiang, H.Q. Deng, G.Q. Zhong, P. He and N.H. Hu: Chem. J. Chin. Universities Vol. 29 (2008), p.2521.

Google Scholar

[6] J. Shen, Q.Y. Jiang, G.Q. Zhong, Y.Q. Jia and K.B. Yu: Acta Chim. Sinica Vol. 65 (2007), p.1588.

Google Scholar

[7] G.Q. Zhong, M.J. Chen, Q.Y. Jiang and Z.P. Zhang: J. Synth. Cryst. Vol. 39 (2010), p.281.

Google Scholar

[8] J.R. Eveland and K.H. Whitmire: Inorg. Chim. Acta Vol. 249 (1996), p.41.

Google Scholar

[9] G.G. Briannd, N. Burford, T.S. Cameron and W. Kwiatkowski: J. Am. Chem. Soc. Vol. 120 (1998), p.11374.

Google Scholar

[10] G. Cantos, C.L. Barbieri, M. Iacomini, P.A.J. Gorin and L.R. Travassos: Biochem. J. Vol. 289 (1993), p.155.

Google Scholar

[11] N.N. Greewood and A. Earnshaw: Chemistry of the Elements (Pergamon Press, Oxford 1984).

Google Scholar