Catalytic Activity of SWNTs/Pd Catalyst in Suzuki Reaction

Abstract:

Pd catalyst is very active in Suzuki reaction. As a heterogeneous catalyst, SWNTs/Pd shows highly catalytic ability with Suzuki reaction. We will demonstrate the effect of catalyst’s amount, the reaction time and temperature on Suzuki reaction in this work. In comparison, a control experiment used commercial Pd/C as catalyst in Suzuki reaction has been done. An optimum reaction condition of about reacting 60 min at 50°C with 5% (mass%) catalyst is confirmed finally, and a better catalytic ability of SWNTs/Pd than commercial Pd/C is also observed.

• Periodical: Advanced Materials Research (Volumes 284-286)
• Pages: 2404-2408
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.284-286.2404
• Online since: July 2011
• Authors: You Ming Cao
• Keywords: Catalysis, Loading, Pd, Suzuki Reaction, SWNTs

References

[1] N. Miyaura, T. Yanagi, A. Suzuki. Synthetic Communications [J], 1981, 11(7): 513-519

[2] N. Miyaura, A. Suzuki. Chemical Reviews [J], 1995, 95(7): 2457-2483

[3] A. Suzuki. Journal of Organometallic Chemistry [J], 1999, 576(1-2): 147-168

[4] A. Suzuki. Proceedings of The Japan Academy Series B [J], 2004, 80(8): 359-371

[5] S. Kotha, K. Lahiri, D. Kashinath. Tetrahedron [J] , 2002, 58(48): 9633-9695

DOI: 10.1016/s0040-4020(02)01188-2

[6] W. A. Herrmann, C. P. Reisinger, M. Spiegler. Journal of Organometallic Chemistry [J], 1998, 557(1):93-96

[7] T. Weakamp, V. P. W. Bohm, W. A. Herrmann. Journal of Organometallic Chemistry [J],1999,585(2):348-352

[8] A. F. Littke, G. C. Fu. Angewandte Chemie International Edition [J], 1998, 37(24): 3387-3388

[9] J. P. Wolfe, I. A. Singer, B. H. Yang, S. L. Buchwald. Journal of the American Chemical Society [J], 1999, 121(41): 9550-9561

[10] D. A. Albisson, R. B. Bedford, S. E. Lawrence, P. N. Scully. Chemical Communications[J], 1998,19:2095-2096

[11] R. B. Bedford, S. M. Draper, P. N. Scully, S. L. Welch. New Journal of Chemistry[J],2000, 24(10): 745-747

[12] C. Dupuis, K. Adiey, L. Charruault, V. Michelet, M. Savignac, J. P. Genet. Tetrahedron Letters [J], 2001, 42(37): 6523-6526

DOI: 10.1016/s0040-4039(01)01301-6

[13] J. H. Kim, J. W. Kim, M. Shokouhimehr, Y. S. Lee. The Journal of Organic Chemistry[J], 2005, 70(17): 6714-6720

[14] L. Liu, Y. Zhang, Y. Wang. The Journal of Organic Chemistry[J], 2005, 70(15): 6122-6125

[15] S. P. Stanforth. Tetrahedron [J], 1998, 54(3-4): 263-303

[16] X. W. Zhao, Y. C. Cui, J. W. Zhang. Chinese Journal of Organic Chemistry[J], 2007,27(5): 597-601

[17] I. Fenger, C. L. Drain. Tetrahedron Letters[J], 1998, 39(24): 4287-4290

[18] C. A. Parrish, S. L. Buchwald. The Journal of Organic Chemistry[J], 2001, 66, 3820

[19] H. J. Li, L. Feng, L. H. Guan, Z. J. Shi, Z. N. Gu. Solid State Communications [J], 2004; 132(3-4): 219-244

[20] Z. J. Shi, Y. F. Lian, F. H. Liao, X. H. Zhou, Z. N. Gu. Zhang, Y. G.; Iijima, S. Solid State Communications[J], 1999, 112(1): 35-37

DOI: 10.1016/s0038-1098(99)00278-1

[21] A. S. Aricò, A. K. Shukla, H. Kim, S. Park, M. Min, V. Antonucci. Applied Surface Science[J], 2001, 172(1-2): 33-40

[22] Y. C. Cui, X. W. Zhao, J. W. Zhang, L. Zhang, X. M. Liu. Acta Chimica Sinica, 2006, 64(1): 42-46

[23] J. X. Liu, W. Jiang, Z. S. Wang, Y. Liu, P. Cui,Cui, P. F. S. Li. Rare Metal Materials and Engineering[J], 2008, 37(8): 1364-1368