Theory Calculation of Diffussion Coefficient Based on Molten Slag Structure

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Abstract:

The diffusion coefficients of slag constituents were calculated using Eyring equation. The Urbain slag viscosity calculation method was modified by improving the constiuents dividing method based on slag depolymerisation degree NBO/T calculation. the amphoteric oxides such as TiO2, Cr2O3, Fe2O3, B2O3 and Al2O3 were specifically dividied into glass former part and modifier part, and the diffusion dimension was calculated according to the value of NBO/T. The results of diffusion coefficients showed that, the modified method is more accurate than the Urbain method within the calculation conditions. Based on the modified diffusion coefficient calculation method, ladle slag composition was optimized to enhance the deoxidization rate.

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Advanced Materials Research (Volumes 284-286)

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411-415

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July 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] W. Klaus, M. Stuart, N. Mehele, et al: State of the Art and Process Technology in Clean Steelmaking, International Iron and Steel Institute, (2004)

Google Scholar

[2] I.H. Jung: Calphad, Vol.34 (2010), p.332

Google Scholar

[3] V. Martin, G.S Shannon and S. Seetharaman: ISIJ Inter., Vol. 46 (2006), p.450

Google Scholar

[4] K.C. Moon, H.P. Joo and J.M. Dong: ISIJ Inter., Vol. 50 (2010), p.324

Google Scholar

[5] W. Liu, Q.H. Wang. The manufacturing technique and equipment of iron-alloy, metallurgy industry press, Beijing, China (2009)

Google Scholar

[6] B.O. Mysen: Geochimica et Cosmochimica Acta, Vol. 70 (2006), p.2337

Google Scholar

[7] B.O. Mysen, M.J. Toplis: American mineralogist, Vol. 92 (2007), p.933

Google Scholar

[8] R. Christian, W. Achim: Chemical Geology, Vol. 213 (2004), p.125

Google Scholar

[9] N. Iwamoto, Y.Makino: Journal of Non-Crystalline Solids, Vol. 34 (1979), p.381

Google Scholar

[10] B.O. Mysen: American mineralogist, Vol. 92 (2007), p.844

Google Scholar

[11] J.F. Stebbins, Z. Xue: Nature, Vol. 390 (1997), p.60

Google Scholar

[12] W.E. Jackson, F.Y. Farges, M. Eager, et al: Geochem et Cosmochim Acta, Vol. 69 (2005), p.4315

Google Scholar

[13] S. Gerlach, O. Claußen and C. Rüssel: Journal of Non-Crystalline Solids, Vol.240 (1998), p.110

Google Scholar

[14] P.V. Riboud, Y. Roux, D. Lucas, et al: Metallweiterverarb, Vol.19 (1981), p.859

Google Scholar

[15] G. Urbain, F. Cambier, M. Deletter, et al: British Ceramic Transactions, Vol. 80 (1981), p.139

Google Scholar

[16] T. Dunn: Diffusion in silicate melts in short course in silicate melts. Edit CM Scarfe. Publ. Mineralogical Soc., Canada, Ottawa, Ont. 1986, Chapter 3, 57-92.

Google Scholar

[17] J. Henderson, L. Yang, G. Dere.: Trans. AIME, Vol. 221 (1996), p.56

Google Scholar

[18] T. Saito, K.Maruya: Sci. Rep. Res. Inst. Tohohu Univ. A ,Vol.10 (1958), p.306

Google Scholar