PVDF-HFP/PVC Blend Based Lithium Ion Conducting Polymer Electrolytes

N.H Basri; S Ibrahim; Nor Sabirin Mohamed

doi:10.4028/www.scientific.net/AMR.287-290.100

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 287-290PVDF-HFP/PVC Blend Based Lithium Ion Conducting...

PVDF-HFP/PVC Blend Based Lithium Ion Conducting Polymer Electrolytes

Abstract:

Flexible free standing polymer electrolyte films have been successfully prepared using a blend of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and poly(vinyl chloride) (PVC) doped with lithium perchlorate (LiClO₄). The conductivity of the film was influenced by salt concentration and the degree of crystallinity. An optimum room temperature conductivity obtained was 2.10 x 10^-4 S cm^-1 for PVDF-HFP/PVC containing 35 wt.% LiClO₄. The temperature-dependent conductivity of the polymer films exhibited VTF-type behaviour.

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Periodical:

Advanced Materials Research (Volumes 287-290)

Pages:

100-103

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.287-290.100

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Online since:

July 2011

Authors:

N.H Basri, S Ibrahim, Nor Sabirin Mohamed

Keywords:

Differential Scanning Calorimetry (DSC), Ionic Conductivity, Polymer Blend, Polymer Electrolyte

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