Synthesis and NLO Properties of Calix[4]Arene Derivatives

Abstract:

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A novel calix[4]arene chromophore 1 was synthesized by introduction of two D-π-A units (4-nitrophenyl)azophenyloxy groups) on the lower rim of calix[4]arene. The measurement results of hyper-Rayleigh scattering (HRS) and UV-vis spectra show that the static first molecular hyperpolarizability of the chromophore 1 is more than two times that of the corresponding mono-D-π-A unit reference compound 4-(4-nitrophenylazo)phenol 2, without causing red-shift of absorption band.

Info:

Periodical:

Advanced Materials Research (Volumes 299-300)

Edited by:

Jianzhong Wang and Jingang Qi

Pages:

452-455

DOI:

10.4028/www.scientific.net/AMR.299-300.452

Citation:

M. F. Fang and G. Y. Lu, "Synthesis and NLO Properties of Calix[4]Arene Derivatives", Advanced Materials Research, Vols. 299-300, pp. 452-455, 2011

Online since:

July 2011

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Price:

$35.00

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