Irradiation Modification of Epoxidized Natural Rubber/Ethylene Vinyl Acetate/Carbon Nanotubes Nanocomposites

Article Preview

Abstract:

The effect of irradiation on the mechanical properties of Epoxidized Natural Rubber/Ethylene Vinyl Acetate/Carbon Nanotubes (ENR/EVA/CNTs) nanocomposites were investigated. CNTs at various amount (2, 3, 4 and 6 wt%) were incorporated into ENR50 by solvent casting method. The ENR/CNTs were then blended with EVA by mixing in a Brabender Plasticoder at 120°C. Next, the samples were irradiated by using electron beam with 3 MeV electron beam machine in a dose range of 50 to 200 kGy. The mechanical properties such as tensile strength (Ts), modulus at 100% elongation (M100), elongation at break (Eb) and hardness of reinforced ENR/EVA/CNTs nanocomposites were studied as a function of radiation dose. It was found that, the Ts and M100 has increased almost 2 times compared to the nanocomposites without irradiation up to 150 kGy dose of radiation, and a downward trend thereafter. Gel fraction further confirmed the powerful energy of electron beam radiation result in irradiation-induced crosslinking and further enhanced mechanical properties of the nanocomposites.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

427-433

Citation:

Online since:

October 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Allaoui, A. & El Bounia, N.: eXPRESS Polymer Letters (2009), 3(9), pp.588-594.

Google Scholar

[2] Gelling, I.R.: Natural Resources (1991), 6 (3), pp.184-205.

Google Scholar

[3] Margaritis, A.G. & Kalfoglou, N.K.: Polymer (1987), 28(3), pp.497-502.

Google Scholar

[4] Mohamad, Z., Ismail, H., Ratnam, C.T.: Polymer Degradation and Stability (2006), xx, pp.1-8.

Google Scholar

[5] Ratnam, C.T., Zahid, A., Hanafi, I.: Polymer-Plastics Technology and Engineering (2006), 45, pp.555-559.

Google Scholar

[6] Charlesby, A.: Atomics (1954), 5(1), pp.12-21.

Google Scholar

[7] Ratnam, C.T., Nasir, M., Baharin, A., Zaman, K.: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms (2000), 171(4), pp.455-464.

DOI: 10.1016/s0168-583x(00)00301-3

Google Scholar

[8] Poh, B.T. & Lee, K.S.: European Polymer Journal (1994), 30(1), pp.17-23.

Google Scholar

[9] Sharif, J., Aziz, S.A.S.H., Hashim. K.: Radiation Physics and Chemistry (2000), 58(2), pp.191-195.

Google Scholar

[10] Datta, S.K., Bhowmick, A. K, Chaki, T.K., Majali, A.B., Despande, R.S.: Polymer (1996), 37(1), pp.45-55.

DOI: 10.1016/0032-3861(96)81598-9

Google Scholar

[11] Banik, I. & Bhowmick, A.K.: Radiation Polymer Chemistry (1999), 54, pp.135-142.

Google Scholar

[12] Ratnam, C.T., Kamaruddin, S., Sivachalam, Y., Talib, M., Yahya, N.: Polymer Testing (2006), 25(4), pp.475-480.

DOI: 10.1016/j.polymertesting.2006.01.012

Google Scholar

[13] Sharif, J., Zaman, K., Zin, W.M.: Radiation Physics and Chemistry (2007), 76, pp.1698-1702.

Google Scholar

[14] Datta, S.K., Bhowmick, A. K, Chaki, T.K., Majali, A.B., Despande, R.S.: Polymer (1996), 37(1), pp.45-55.

DOI: 10.1016/0032-3861(96)81598-9

Google Scholar

[15] Ang, C.H., Garnett, J.L., Levot, R., Long, M.A.: Applied Polymer Science (1982), 27(12), pp.4893-4895.

Google Scholar