Composite FeF3•3H2O/C Cathode Material for Lithium Ion Battery

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Abstract:

Composite FeF3•3H2O/C was prepared by mixing FeF3•3H2O with acetylene black through high-energy milling, and used as cathode material for Li-ion battery. The structure and the morphology of the as-prepared composite FeF3•3H2O/C were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). When compared with FeF3•3H2O synthesized by a liquid-phase method, the composite FeF3•3H2O/C had no distinct difference in crystal structure, but shows that a well distributed particle size of 100~1000nm. The electrochemical performances of FeF3•3H2O/C composite were evaluated by charge-discharge test and cyclic voltammetery (CV). With a current density of 23.7mAg-1 in the voltage range of 2.0~4.5V at room temperature, the FeF3•3H2O/C composite achieved a maximum discharge capacity of 112 mAhg-1, as well as a good cycling performance.

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Advanced Materials Research (Volumes 391-392)

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1090-1094

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December 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] F.T. Wagner, B. L. Mathias: J. Phys. Chem. Lett. Vol. 1 (2010), p.2204.

Google Scholar

[2] P.G. Bruce: Solid State Ionics Vol. 179(2008), p.752.

Google Scholar

[3] F. Wu: Mater. China Vol. 28 (2009), p.41.

Google Scholar

[4] L.J. Jiang and X.J. Zhang: Mater. China Vol. 28 (2009), p.51.

Google Scholar

[5] G.G. Amatucci and N. Pereira: J. Fluorine Chem. Vol. 128 (2007), p.243.

Google Scholar

[6] X.P. Gao and H.X. Yang: Energy Environ. Sci. Vol. 3 (2010), p.174.

Google Scholar

[7] R. Prakash and A.K. Mishra: J. Mater. Chem. Vol. 20 (2010), p.1871.

Google Scholar

[8] H.N. Seiger, A.E. Lyall and R.C. Shair, in: Proceedings of the 6th International Symposium on Power Sources 2: Develop Non-Mech Elec Power Sources, (1970).

Google Scholar

[9] F. Badway, N. Pereira and F. Cosandey: J. Electrochem. Soc. Vol. 150 (2003), p. A1209.

Google Scholar

[10] F. Badway, N. Pereira and F. Cosandey: J. Electrochem. Soc. Vol. 150 (2003), p. A1318.

Google Scholar

[11] Y. Makimura and J.M. Tarascon: Appl. Surf. Sci. Vol. 252 (2006), p.4587.

Google Scholar

[12] T. Li and L. Li: J. Phys. Chem. C Vol. 114 (2010), p.3190.

Google Scholar

[13] W. Wu and X.Y. Wang: J. Alloys Compd. Vol. 486 (2009), p.93.

Google Scholar

[14] W. Wu and X.Y. Wang: Mater. Lett. Vol. 63 (2009), p.1788.

Google Scholar

[15] W. Wu and X.Y. Wang: J. Funct. Mater. Vol. 11 (2008), p.1824.

Google Scholar