Electrochemical Performance of Polypyrrole/Multi-Walled Carbon Nanotubes Composites for Supercapacitors Electrodes

Article Preview

Abstract:

Nanocomposites supercapacitors electrodes are synthesized by homogeneously coating the nano-structured polypyrrole (PPy) on multi-walled carbon nanotubes (MWCNTs) via a facile electrochemical method. The capacitance properties of the composites are evaluated by cyclic voltammetry (CV) and galvanostatic charge/discharge techniques. The results show that the porous composites structure exhibit a remarkable specific capacitance of 674 F g-1 at a current density of 2 A g-1. Electrochemical experiments indicate that the high specific capacitance is associated with uniform PPy coating. Moreover, the composites present a nearly ideal rectangular shape of cyclic voltammetry characteristics. The stability of the composites electrode is also examined and only 10% capacitance decrease after 800 cycles. This technique provides a feasible solution for developing high-performance electrical energy storage devices.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 399-401)

Pages:

1415-1418

Citation:

Online since:

November 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] B.J. Lee, S.R. Sivakkumar, J.M. Ko, J.H. Kim, S.M. Jo and D.Y. Kim: J. Power Sources Vol. 168 (2007), p.546

Google Scholar

[2] C.C. Hu, K.H. Chang and C.C. Wang: Electrochim. Acta Vol. 52 (2007), p.4411

Google Scholar

[3] G.W. Yang, C.L. Xu and H.L. Li: Chem. Comm. Vol. 48 (2008), p.6537

Google Scholar

[4] H.L. Wang, Q.L. Hao, X.J. Yang, L.D. Lu and X. Wang: Electrochem. Commun. Vol. 11 (2009), p.1158

Google Scholar

[5] Q.F.Wu, K.X. He, H.Y. Mi and X.G. Zhang: Mater. Chem. Phys. Vol. 101 (2007), p.367

Google Scholar

[6] T.F. Otero and J. Padilla: J. Electroanal. Chem. Vol. 561 (2004), p.167

Google Scholar

[7] Y.P. Fang, J.W. Liu, D.J. Yu, J.P. Wicksted, K. Kalkan, C.O. Topal, B.N. Flanders, J.D. Wu and J. Li, J. Power Sources Vol. 195 (2010), p.674

DOI: 10.1016/j.jpowsour.2009.07.033

Google Scholar

[8] Y.K. Lee, K.J. Lee, D.S. Kim, D.J. Le and J.Y. Kim, Synth. Met. Vol. 160 (2010), p.814

Google Scholar

[9] W. Sugimoto, H. Iwata, Y. Yasunaga, Y. Murakami and Y. Takasu: Angew. Chem., Int. Ed. Vol. 42 (2003), p.4092

Google Scholar

[10] R. Kotz and M. Carlen: Electrochim. Acta Vol. 45 (2000), p.2483

Google Scholar