Magnetite and Anti-Microbial Properties of Ag2O-CaO-Fe2O3-SiO2 Glass-Ceramic by Sol-Gel Method

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Abstract:

Ag2O-CaO-Fe2O3-SiO2 glass-ceramic was prepared by the sol-gel method. Differential scanning calorimetry (DSC), X-ray diffraction (XRD), scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM) were used to investigate crystallization process of Ag2O-CaO-Fe2O3-SiO2 glass. The kinetic results show that the values of the activation energy and frequency factor of the glass are 441.991 KJ/ mol and 1.58×1020, respectively. And the dimensionality of crystal growth, n, decreases as the heating rate increases. The crystalline phases of the glass-ceramic are magnetite, wollastonite and minor hematite. The saturation magnetization and coercive force of the heat-treated glass are 0.08 Wb/m2 and 14 KA/m at room temperature. The glass-ceramic has some capacity of anti-microbial.

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Advanced Materials Research (Volumes 399-401)

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869-872

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November 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Atalay, H. I. Adiguzel, F. Atalay: Infrared absorption study of Fe2O3-CaO-SiO2 glass ceramics. Mat. Sci. Eng. A-Struct. Vol. 304 (2004), p.796

DOI: 10.1016/s0921-5093(00)01572-0

Google Scholar

[2] A.Yasumori, A.Koike, Y. Kameshima, K.Okada, H. Nishio: Magnetic anisotropy of phase-separated CaO-Fe3O4-SiO2 glasses prepared from a two-liquids immiscible melt. J. Non-Cryst. Solids Vol. 297 (2002), p.239

DOI: 10.1016/s0022-3093(01)00938-3

Google Scholar

[3] Y. K. Lee, S. Y. Choi.: Crystallization and Properties of Fe2O3-CaO-SiO2 Glasses. J. Am. Ceram. Soc. Vol. 79 (1996), p.992

Google Scholar

[4] Y. K. Lee, S. Y. Choi.: Controlled nucleation and crystallization in Fe2O3-CaO-SiO2 glass. J. Mater. Sci. Vol. 32 (1997), p.431

Google Scholar

[5] M.G. Ferreira da Silva, M.A. Valente: Crystallization and properties of sol-gel derived 10Fe2O3-10Al2O3-80SiO2 glass-ceramics. J. Non-Cryst. Solids Vol. 232 (1998), p.409

DOI: 10.1016/s0022-3093(98)00423-2

Google Scholar

[6] I. Manjubala, T.S. Sampath Kumar: Effect of TiO2-Ag2O additives on the formation of calcium phosphate based functionally graded bioceramics. Biomaterials Vol. 21 (2000), p. (1995)

DOI: 10.1016/s0142-9612(00)00092-2

Google Scholar

[7] J. Livage: Sol-gel processes. Curr. Opin. Solid. St. M. Vol. 2 (1997), p.132

Google Scholar

[8] P. Saravanapavan, L. L. Hench: Mesoporous calcium silicate glasses. J. Non-Cryst. Solids Vol. 318 (2003), p.1

DOI: 10.1016/s0022-3093(02)01864-1

Google Scholar

[9] M. Laczka, K. Cholewa, A. Laczka-Osyczka: Gel-derived powders of CaO-P2O5-SiO2 system as a starting material to production of bioactive ceramics. J. Alloy. Compd. Vol. 248 (1997), p.42

DOI: 10.1016/s0925-8388(96)02648-5

Google Scholar

[10] G. Laudisio, F. Branda: Sol-gel synthesis and crystallization of 3CaO∙2SiO2 glassy powders. Thermochim. Acta. Vol. 370 (2001), p.119

DOI: 10.1016/s0040-6031(00)00786-3

Google Scholar

[11] H. E. Kissinger: Reaction kinetics in differential thermal analysis. Anal. Chem. Vol. 29 (1957), p.1702

Google Scholar

[12] J. A. Augis, J. E. Bennett: Calculation of the Avrami Parameters for Heterogeneous Solid-State Reactions Using a Modification of the Kissinger Method. J. Therm. Anal. Vol. 13 (1978), p.283

DOI: 10.1007/bf01912301

Google Scholar

[13] B. Yu, K. Liang, S. Gu: Effect of ZrO2 on crystallization of CaO-P2O5-SiO2 glasses. Ceram. Int. Vol. 28 (2002), p.695

DOI: 10.1016/s0272-8842(02)00024-x

Google Scholar