Effect of Acrylic Acid Treated Rice Husk Silica on Properties of Poly (butylene adipate-co-terephthalate) (PBAT) Composites

Article Preview

Abstract:

In this work, rice husk silica (RHS), obtained from rice husk waste, was used as a reinforcing filler for preparing PBAT composites. In order to facilitate interfacial adhesion between PBAT matrix and RHS filler, the RHS surface was treated with acrylic acid (AA) at a reaction temperature of 140°C. The RHS to AA weight ratio was fixed while the reaction times were varied between 3-24 h. TGA results and FTIR spectra indicated the appearance of AA molecules on RHS surface. Untreated RHS (U-RHS) and AA treated RHS (AA-RHS) were used to produce PBAT composites. The filler content was 30 wt%. Tensile properties and impact strength of AA-RHS/PBAT composites were higher than those of U-RHS/PBAT composite. As revealed by SEM micrographs, AA-RHS was well dispersed in PBAT matrix and the interfacial adhesion between RHS surface and PBAT matrix was improved.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

81-85

Citation:

Online since:

November 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] O. Martin and L. Averous: Polymer. Vol. 42 (2001), p.6209.

Google Scholar

[2] U. Witt et al.: Chemosphere. Forum Vol. 44 (2001), p.289.

Google Scholar

[3] F.T. Tan, D.G. Cooper, M. Maric and J.A. Nicell: Polym. Degrad. Stab. Vol. 93 (2008), p.1479.

Google Scholar

[4] F. Signori, M. -B. Coltelli and S. Bronco: Polym. Degrad. Stab. Vol. 94 (2009), p.74.

Google Scholar

[5] V.P. Della, I. Kuhn and D. Hotza: Mater. Lett. Vol. 57 (2002), p.818.

Google Scholar

[6] J. Wittayakun, P. Khemthong and S. Prayoonpokarach: Korean J. Chem. Eng. Vol. 25 (2008), p.861.

Google Scholar

[7] S. Yan et. al.: Polymer. Vol. 48 (2007), p.1688.

Google Scholar

[8] J. Phosee, J. Wittayakun, N. Suppakarn, Proceedings of Pure and Applied Chemistry International Conference 2010, Ubon Ratchathani, Thailand. (2010), p.515.

Google Scholar

[9] X. Lu, X. Lv, Z. Sun and Y. Zheng: Eur. Polym. J. Vol. 44 (2008), p.2476.

Google Scholar

[10] D. Stojanovic et al., J. Supercrit. Fluids Vol. 52 (2010), p.276.

Google Scholar

[11] K. Suzuki, S. Siddiqui, C. Chappell, J.A. Siddiqui and R.M. Ottenbrite: Polym. Adv. Technol. Vol. 11 (2000), P. 92.

Google Scholar

[12] J.C. Tang, H.C. Yang, S.Y. Chen and Y.W. Chen-Yang: Polym. Compos. Vol. 28 (2007), p.575.

Google Scholar

[13] A. Zhu, A. Cai, W. Zhou and Z. Shi: Appl. Sur. Sci. Vol. 254 (2008), p.3745.

Google Scholar