Synthesis and Crystal Structure of the Cobalt (II) Complex with Mixed-Ligand

Abstract:

The Cobalt (Ⅱ) Complex constructed with 5-nitroisophthalic acid and 2,2’-bibenzimidazole, [Co(H2bibim)2( 5-nipa)] (1), (H2bibim =2,2’-bibenzimidazole, 5-nipa=5-nitroisophthalic acid) have been synthesized by hydrothermal methods and structurally characterized by elemental analysis, IR and X-ray single crystal diffraction. Complex 1 has six coordinated by two H2bibim ligands and one 5-nitroisophthalic acid groups that is further connected though intermolecular hydrogen bonds and resulting in a three-dimensional (3D) network.

• Periodical: Advanced Materials Research (Volumes 418-420)
• Pages: 59-62
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.418-420.59
• Online since: December 2011
• Authors: Yan Yang, Liu Ting Yan, Xiao Li, Rong Huan Qin, Wen Gui Duan
• Keywords: Cobalt(II) Complex, Crystal Structure, Mixed-Ligand

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DOI: 10.1039/b910490a

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