Study of CO2 Hydrate Growth Process Based on Diffusion-Controlled Reaction

Ni Liu; Ju Li; Dao Ping Liu

doi:10.4028/www.scientific.net/AMR.433-440.188

Paper Titles

Effect of Hydrogen Addition into Methane-Air Mixture on Combustion Pressure
p.166

Photocatalytic Degradation of Bisphenol A in Aqueous Suspensions of Titanium Dioxide
p.172

Synthesis and Characterization of Quaternary Ammonium-Based Ionic Liquid
p.178

The Influence of Coexisting Ions on Adsorption-Flotation of Pb2+ in Water by Gordona Amarae
p.183

Study of CO₂ Hydrate Growth Process Based on Diffusion-Controlled Reaction
p.188

Mechanism Analysis on Performance Enhancement of Ammonia Bubble Absorption by Nanofluid
p.195

Research in Testing of Loess Foundation Pile Hysteretic Property under Horizontal Cyclic Load
p.202

Research on Settlement of Road on Very Soft Soil Foundation
p.207

Process Analysis of Hydrogen Storage in the Hydrate Form by Utilization of Liquefied Natural Gas Cold Energy
p.215

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 433-440Study of CO2 Hydrate Growth Process Based on...

Study of CO₂ Hydrate Growth Process Based on Diffusion-Controlled Reaction

Abstract:

A one-dimensional mathematical model of mass transfer during CO2 gas hydrate film formation at the boundary between the gas and water is established by analyzing the process of the static system. According to the model, we can get the concentration distribution of free CO2 in the hydrate film along with the time, and the conversion rate of hydrate with time can also be obtained. The results calculated at specific experiment condition in the system are analyzed. It indicates that the conversion rate can reach about 85% after 10 hours under static condition with 3.5MPa pressure and 0.5°C temperature by pure water when the initial reaction liquid depth is 20 mm

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 433-440)

Pages:

188-194

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.433-440.188

Citation:

Cite this paper

Online since:

January 2012

Authors:

Ni Liu, Ju Li, Dao Ping Liu

Keywords:

CO₂ Hydrate, Conversion Rate, Mass Transfer, Mathematical Models

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] Xiao Yang, Liu Daoping, Xie Yingming, etc. Recent research progresses in CO2 hydrate [J]. Natural Gas Geoscince, 2007, 4(18): 607-610.

Google Scholar

[2] Liu Ni, Zhang Guochang, R E Rogers. Experimental study of CO2 gas hydrates formation [J]. Journal of University of Shanghai for Science and Technology, 2007, 4(29): 405-408.

Google Scholar

[3] Hirai, S., Okazaki, K., Araki, N., etc. Transport phenomena of liquid CO2 in pressurized water flow with clathrate-hydrate at the interface. Energy Conversion and Management, 1996, 37: 1073-1078.

DOI: 10.1016/0196-8904(95)00300-2

Google Scholar

[4] Jorge Gabitto, Costas Tsouris. Dissolution mechanisms of CO2 hydrate droplets in deep seawaters. Energy Conversion and Management , 2006, 47: 494–508.

DOI: 10.1016/j.enconman.2005.05.016

Google Scholar

[5] Keiichi Ogasawara, Akihiro Yamasaki, and Ho Teng. Mass Transfer from CO2 Drops Traveling in High-Pressure and Low-Temperature Water. Energy & Fuels 2001, 15: 147-150.

DOI: 10.1021/ef000151n

Google Scholar

[6] Takaaki Mochizuki., Yasuhiko H. Mori. Clathrate-hydrate film growth along water/hydrate-former phase boundaries—numerical heat-transfer study. Journal of Crystal Growth , 2006, 290: 642–652.

DOI: 10.1016/j.jcrysgro.2006.01.036

Google Scholar

[7] Englezos, P., Kalogerakis, N.E., Dholabhai P.D., etc. Kinetics of formation of methane and ethane gas hydrates. Chemical Engineering Science, 1987, 42: 2647- 2658.

DOI: 10.1016/0009-2509(87)87015-x

Google Scholar

[8] Xu Xinya, Liu Daoping, Pan Yunxian, etc. Kinetics of gas hydrate formed from water droplet [J]. Journal of Engineering Thermophysics, 2006, 1(27): 193-196.

Google Scholar