Effects of Water Vapor on the Oxidation Behaviors of Cr-Al-N Coatings

Article Preview

Abstract:

Cr1-xAlxN coatings with different aluminum content were deposited on K38G alloy by reactive magnetron sputtering method. Oxidation behaviors of these coatings were investigated at 1000°C in air+10 vol.% water vapor. The surface morphologies and the microstructure of the oxide scales were analyzed by SEM and XRD, respectively. The results showed that the oxidation of the Cr1-xAlxN coatings in the wet air also obeyed the parabolic law; however, compared to that in the dry air, existing of 10 vol. % water vapor increased the parabolic rate constants of the coatings. It was believed that the accelerating of the oxidation rates was owing to easily outwards diffusion of Cr through the looser and coarser oxide scales formed on the surface of the coatings when oxidized in wet air.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 476-478)

Pages:

2083-2086

Citation:

Online since:

February 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] N. K. Othman, N. Othman, J. Zhang, et al. : Corros. Sci., vol. 51(2009), p.3039.

Google Scholar

[2] H. Asteman, J. E. Svensson and L. G. Johansson: Corros. Sci., vol. 44(2002), p.2635.

Google Scholar

[3] Y. Makino and K. Nogi: Surf. Coat. Tech., vol. 98 (1998), p.1008.

Google Scholar

[4] M. Uchida, N. Nihira, A. Mitsuo, et al.: Surf. Coat. Tech., vol. 177-178 (2004), p.627.

Google Scholar

[5] H. Willmann, P. H. Mayrhofer, et al.: Scripta Materialia vol. 54 (2006), p.1847.

Google Scholar

[6] M. Zhu, M. Li and Yanchun Zhou: Surf. Coat. Tech., vol. 201 (2006), p.2878.

Google Scholar

[7] M. Zhu, M. Li, S. W. Duo, et al.: J. Mat. Sci. and Tech., vol. 23 (2007), p.373.

Google Scholar

[8] M. Zhu, M. Li and Y. Zhou: Mat. Corros., vol. 61(2010), p.939.

Google Scholar

[9] M. Zhu and M. Li: Adv. Mat. Res., vol. 177(2011), p.249.

Google Scholar

[10] N. K Othman, J. Zhang and D. Young: Corros. Sci., 52(2010), p.2827.

Google Scholar

[11] H. Asteman, J. E. Svensson and L. G. Johansson:Oxid. Mat., vol. 57(2002), p.193.

Google Scholar