Temperature Dependence of LiMn₂O₄ Prepared by a Solution Combustion Synthesis in the System of Acetate Salts and Acetic Acid

Abstract:

Spinel LiMn2O4 have been prepared by the solution combustion synthesis method using acetate salts as raw materials and acetic acid as fuel. The phase compositions of the as-prepared products were determined by X-ray diffraction (XRD). The electrochemical performance of the products was tested by using a coin-type half battery versus lithium metal foil as anode material. XRD results suggested that the purities of the products prepared at 500oC are higher than these of the products prepared at 600oC. For the products prepared at 500oC, the purities of the products increase with increasing acetic acid ratios. But for the products prepared at 600oC, the purities of the products decrease with increasing acetic acid ratios. The performance tests indicated that the electrochemical performances of the products prepared at 500oC are better than these of the products prepared at 600oC. The product prepared at 500oC with the acetic acid ratio of 1.0 gets the best performance. The initial capacity of it reaches to 124.8mAh/g at the current density of 75mA/g, and after 50 cycles, the capacity retention is 93.7%.

• Periodical: Advanced Materials Research (Volume 485)
• Pages: 465-468
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.485.465
• Online since: February 2012
• Authors: Li Li Zhang, Gui Yang Liu, Jun Ming Guo, Bao Sen Wang, Ying He
• Keywords: Cathode, Lithium-Ion Battery, Solution Combustion Synthesis (SCS), Spinel

References

[1] J.Y. Luo, Y.G. Wang, H.M. Xiong, et al: Chem. Mater. Vol. 19 (2007), p.4791.

[2] C.J. Curtis, J.X. Wang, D.L. Schulz: J. Electrochem. Soc. Vol. 151 (2004), p.590.

[3] J.H. Choy, D.H. Kim, C.W. Kwon, et al: J. Power Sources Vol. 77 (1999), p.1.

[4] S. Chitra, P. Kalayani, T. Mohan, et al: J. Electroceram. Vol. 3-4 (1999), p.433.

[5] S. Chitra, P. Kalayani, T. Mohan, et al: J. Electrochem. Vol. 3-4 (1999), p.433.

[6] K.M. Lee, H.J. Choi and J.G. Lee: J Mater. Sci. Lett. Vol. 20 (2001), p.1309.

[7] W.S. Yang, G. Zhang, J.Y. Xie, et al: J. Power Sources Vol. 80-82 (1999), p.412.

[8] G.Y. Liu, J.M. Guo and B.S. Wang: Adv. Mater. Res. Vols. 143-144 (2011), p.125.

[9] G.Y. Liu, J.M. Guo and Y.N. Li: Adv. Mater. Res. Vols. 140-162 (2011), p.554.

[10] G.Y. Liu, D.W. Guo, J.M. Guo, et al: Key Eng. Mat. Vols. 368-372 (2008), p.293.

[11] A.B. Yuan, L. Tian, W.M. Xu, et al: J. Power Sources Vol. 195 (2010), p.5032.