Surface Morphology of Metal Oxide SnO2 under Different Concentrations of Oxygen by Thermal Evaporation Method

Article Preview

Abstract:

SnO2 has been successfully grown on Si substrate using a thermal evaporation method, under different percentages of argon and oxygen gases. High purity Sn metal was used as reactants with deposition temperature were set at 900°C. Different oxygen concentrations range between 1.6 and 10% were used during thermal evaporation process. The as-prepared metal oxides were analyzed using SEM-EDS, XRD and UV-VIS. SnO2 nanowhiskers were obtained at lower oxygen concentrations (1.6 to 6% oxygen), while nanowires structures were formed at higher oxygen percentages. XRD results revealed SnO2 produced were highly crystalline and no other impurity phase diffraction peaks were detected. EDS analysis revealed that only Sn and O elements were present in the sample which are consistent with XRD results. UV-VIS result revealed that the optical band gap energy of the metal oxides produced have low significant effect with increasing oxygen concentration. Optical band gap energy for was within 3.3 eV, which was lower than the optical band gap energy of bulk SnO2.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

266-270

Citation:

Online since:

April 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Z. L, Wang, Functional oxide nanobelts: Materials, properties and potential applications in nanosystems and biotechnology. Annu. Rev. Phys. Chem. 55 (2004) 159-196.

DOI: 10.1146/annurev.physchem.55.091602.094416

Google Scholar

[2] H. W, Kim, S. H, Shim, & C, Lee, SnO2 microparticles by thermal evaporation and their properties. Ceramics International 32 (2006) 943–946.

DOI: 10.1016/j.ceramint.2005.06.015

Google Scholar

[3] M. Zheng, G. Li, X. Zhang, S. Huang, Y. Lei, & L..Zhang, Fabrication and structural characterization of large-scale uniform SnO2 nanowire array embedded in anodic alumina membrane. Chem. Mater. 13 (11) (2001) 3859–3861.

DOI: 10.1021/cm010084q

Google Scholar

[4] Y. Liu,. C. Zheng, W. Wang, C. Yin,. & G. Wang, Synthesis and characterization of rutile SnO2 nanorods. Advanced Materials 13 (24) (2001) 1883-1887.

DOI: 10.1002/1521-4095(200112)13:24<1883::aid-adma1883>3.0.co;2-q

Google Scholar

[5] Y. X. Chen, L. J. Campbell, & W. L. Zhou, Self-catalytic branch growth of SnO2 nanowire junctions. Journal of Crystal Growth 270 (2004) 505–510

DOI: 10.1016/j.jcrysgro.2004.07.011

Google Scholar

[6] L. S Roman, R. Valaski, C. D. Canestraro, E. C. Magalhaes, C. Persson, R. Ahuja, E. F. Silva, I. Pepe, & A. Ferreira,. Optical band-edge absorption of oxide compound SnO2. Applied Surface Science 252 (2006) 5361–5364.

DOI: 10.1016/j.apsusc.2005.12.040

Google Scholar

[7] L. E. Brus, Quantum crystallites and nonlinear optics. Applied Physics A 53(1991) 465-474.

Google Scholar